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Hyperfine Interactions

, Volume 161, Issue 1–4, pp 99–111 | Cite as

Study on Stereochemical Activity of Lone Pair Electrons in Sulfur and Halogen Coordinated Antimony(III) Complexes by 121Sb Mössbauer Spectroscopy

  • Ryuhichi Ohyama
  • Masashi Takahashi
  • Masuo Takeda
Article

Abstract

We have measured 121Sb Mössbauer spectra at 20 K for 52 compounds of antimony(III). An Sb(III) atom with the electron configuration [Kr] 4d 105s 2 has a lone pair electrons. The stereochemical property of the lone pair has been found to depend very much on the kinds of atoms surrounding the antimony atom and the configurations of the coordinating atoms.

Key Words

coordination configuration lone pair electron 121Sb Mössbauer spectroscopy Sb(III) complexes 

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Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • Ryuhichi Ohyama
    • 1
    • 2
  • Masashi Takahashi
    • 1
  • Masuo Takeda
    • 1
  1. 1.Department of Chemistry, Faculty of ScienceToho UniversityChibaJapan
  2. 2.Tama Chemicals Co., Ltd.KawasakiJapan

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