Abstract
This paper reports on the results of investigations into the specific features of the formation of silicate nanosized films from sols based on tetraethoxysilane (hydrolyzed in an acid medium in the presence of inorganic dopants) on the surface of semiconductor materials. The properties of the films thus prepared are analyzed as functions of the synthesis conditions of sols and the conditions of deposition and heat treatment of the films. It is demonstrated that these films can be used in technology for fabricating semiconductor gas sensors based on SnO2.
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REFERENCES
Grebenshchikov, I.V., Vlasov, A.G., Neporent, B.S., and Suikovskaya, N.V., Prosvetlenie optiki (Blooming of Optical Systems), Moscow: Goskhimizdat, 1946.
Borisenko, A.I. and Nikolaeva, L.V., Tonkosloinye stekloemalevye i steklokeramicheskie pokrytiya (Thin-Layer Glass-Enamel and Glass-Ceramic Coatings), Leningrad: Nauka, 1970.
Suikovskaya, N.V., Khimicheskie metody polucheniya tonkikh prozrachnykh plenok (Chemical Methods for Producing Thin Transparent Films), Leningrad: Khimiya, 1971.
Schroeder, H., Deposition of Oxide Films from Organic Solutions, in Physics of Thin Films: Advances in Research and Development, Hass, G. and Thun, R.E., Eds., New York: Academic, 1969, vol. 5. Translated under the title Fizika tonkikh plenok, Moscow: Mir, 1972.
Borisenko, A.I., Novikov, V.V., Prikhod’ko, N.E., Mitnikova, I.M., and Chepik, L.F., Tonkie neorganicheskie plenki v mikroelektronike (Thin Inorganic Films in Microelectronics), Leningrad: Nauka, 1972.
Nikolaeva, L.V. and Borisenko, A.I., Tonkosloinye stekloemalevye i steklokeramicheskie pokrytiya (Thin-Layer Glass-Enamel and Glass-Ceramic Coatings), Leningrad: Nauka, 1980.
Brinker, C.J. and Scherer, G.W., Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing, San Diego: Academic, 1990.
Levy, D. and Esquivias, L., Sol-Gel Processing of Optical and Electrooptical Materials, Adv. Mater., 1995, no. 7, pp. 120–129.
Zhabrev, V.A. and Shultz, M.M., Ceramic and Vitreous Materials: Prospects for the Development, in Steklo i keramika—XXI. Perspektivy razvitiya (Kontseptsiya akademika Shevchenko V.Ya.) [Glass and Ceramics—XXI: Prospects for the Development (The Concept of Academician V.Ya. Shevchenko)], St. Petersburg: Yanus, 2001, pp. 107–175.
Chen, D., Anti-Reflection (AR) Coatings Made by Sol-Gel Processes: A Review, Sol. Energy Mater. Sol. Cells, 2001, vol. 68, pp. 313–336.
Martucci, A., Bassiri, N., Guglielmi, M., Armelao, L., Gross, S., and Pivin, J.C., NiO-SiO2 Sol-Gel Nanocomposite Films for Optical Gas Sensor, J. Sol-Gel Sci. Technol., 2003, vol. 26, nos.1–5, pp. 993–996.
Phani, A.R. and Santucci, S., Structural Characterization of Iron Titanium Oxide Synthesized by Sol-Gel Spin-Coating Technique, Mater. Lett., 2001, vol. 50, pp. 240–245.
Liu, Yu., Cui, T., Sunkam, R.K., Coane, P.J., Vasile, M.J., and Geoettert, J., Novel Approaches to Form and Pattern Sol-Gel Polymethylsilsesquioxane-Based Spin-on Glass Thin and Thick Films, Sens. Actuators, B, 2003, vol. 88, no.1, pp. 75–79.
Zinov’ev, K.V., Vikhlyantsev, O.F., and Gribov, B.G., Preparation of Oxide Films from Solutions and Their Use in Electronics, Obzory Elektron.Tekh., Ser. Mater., Moscow: TsNII Elektronika, 1974, issue 13 (250).
Gribov, B.G., Zaitsevskaya, Z.A., Zvezdochkin, A.P., and Zinov’ev, K.V., Application of the Silicate Films Prepared from Solutions in Planar Technology, Elektron. Prom-st., 1978, no. 1 (61), pp. 44–48.
Zinov’ev, K.V., Solution Compositions for Electronics, Elektron. Prom-st., 1980, nos. 8–9, pp. 93–96.
Shilova, O.A., Chepik, L.F., and Bubnov, Yu.Z., Properties of the Films Prepared from Tetraethoxysilane-Based Solutions as Functions of the Technological Aspects of Their Formation, Zh. Prikl. Khim. (St. Petersburg), 1995, vol. 68, no.10, pp. 1608–1612.
Sviderskii, V.A., Voronkov, M.G., Klimenko, V.S., and Klimenko, S.V., Hydrolytic Polycondensation of Tetraethoxysilane with Metal Salts and Metal Oxides in Sol-Gel Processing, Zh. Prikl. Khim. (St. Petersburg), 1997, vol. 70, no.10, pp. 1698–1703.
Bubnov, Yu.Z., Chepik, L.F., Shilova, O.A., and Vishevnik, L.N., Sol-Gel Technology in Fabrication of Thin-Film Gas Sensors, in Trudy XVII soveshchaniya “Temperaturoustoichivye funktsional’nye pokrytiya” (Proceedings of the XVII Conference “Heat-Resistant Functional Coatings”), St. Petersburg: OOP NIIKh St. Petersburg Gos. Univ., 1997, vol. 1, pp. 99–104.
Khashkovskii, S.V., Chepik, L.F., and Kuznetsova, L.A., Solution Technology for Preparing Vitreous Inorganic Films and Glass-Ceramic Coatings, in Fizikokhimiya silikatov i oksidov (Physical Chemistry of Silicates and Oxides), Shultz, M.M., Ed., St. Petersburg: Nauka, 1998, pp. 277–286.
Shilova, O.A., Bubnov, Yu.Z., and Khashkovskii, S.V., Application and Prospects for the Use of Thin Vitreous Films in Microelectronic Engineering, Vopr. Khim. Khim. Tekhnol. (Nauchno-Tekh. Zh. Ukr. Gos. Khim. Tekhnol. Univ.), 2001, no. 1, pp. 75–80.
Shilova, O.A. and Khashkovskii, S.V., Sol-Gel Method for Preparing Composite Vitreous and Glass-Ceramic Films Based on Inorganic Polymers, Mater. Tekhnol. Instr., 2001, vol. 6, no.2, pp. 64–68.
Shilova, O.A., Hashkovsky, S.V., and Kuznetsova, L.A., Sol-Gel Preparation of Coatings for Electrical, Laser, Space Engineering, and Power, J. Sol-Gel Sci. Technol., 2003, vol. 26, nos.1–3, pp. 687–691.
Shilova, O.A., Spin-on Glass Films for Semiconductor Technology, Surf. Coat., Part B: Coat. Trans., 2003, vol. 86, no.3, pp. 195–202.
Bubnov, Yu.Z. and Shilova, O.A., Nanometer-Sized Vitreous Films for Multifunctional Purposes in Technology for Fabricating Semiconductor Gas Sensors, Tekhnol. Priborostr., 2003, no. 3(7), pp. 60–71.
Shilova, O.A. and Shilov, V.V., Oxide and Hybrid Organic-Inorganic Nanocomposite Materials Prepared by Sol-Gel Method: Synthesis, Properties, and Applications, in Nanosistemy. Nanomaterialy. Nanotekhnologii. Sbornik nauchnykh trudov (Nanosystems, Nanomaterials, and Nanotechnologies: A Collection of Scientific Papers), Shpak, A.P., Ed., Kiev: Akademperiodika, 2003, vol. 1, no.1, pp. 9–83.
Saifullin, R.S. and Saifullin, A.R., Universal’nyi leksikon: khimiya, fizika i tekhnologiya (na russkom i angliiskom yazykakh) [Universal Dictionary: Chemistry, Physics, and Technology (in Russian and English)], Moscow: Logos, 2001 (Federal Special Program: State Support for the Integration of Higher Education and Fundamental Science in 1997–2000).
Yoldas, B.E., Introduction and Effect of Structural Variations in Inorganic Polymers and Glass Networks, J. Non-Cryst. Solids, 1982, vol. 51, no.1, pp. 105–121.
Iler, R.K., The Chemistry of Silica: Solubility, Polymerization, Colloidal and Surface Properties, and Biochemistry of Silica, New York: Wiley, 1979. Translated under the title Khimiya kremnezema, Moscow: Mir, 1982.
Andrianov, K.A., Kremneorganicheskie soedineniya (Organosilicon Compounds), Moscow: Goskhimizdat, 1955.
Voronkov, M.G. and Zgonnik, V.N., Organosilicon Derivatives of Boric Acid, Tris(trialkyl)borates, and Polyorganoborosiloxanes, Zh. Obshch. Khim., 1957, vol. 27, no.6, pp. 1476–1483.
Voronkov, M.G., Mileshkevich, V.P., and Yuzhelevskii, Yu.A., Siloksanovaya svyaz’ (Siloxane Bonding), Novosibirsk: Nauka, 1976.
Voronkov, M.G., Maletina, E.A., and Romes, V.K., Kremnekislorodnye soedineniya nemetallov. Proizvodnye azota i fosfora (Silicon-Oxygen Compounds of Nonmetals: Nitrogen and Phosphorus Derivatives), Novosibirsk: Nauka, 1988.
Zhao, G., Kozuka, H., and Sakka, S., Preparation of TiO2 Coating Films Containing Pd Fine Particles by Sol-Gel Method, J. Sol-Gel Sci. Technol., 1995, vol. 4, pp. 37–47.
Langlet, M., Jenouvrier, P., Kim, A., Manso, M., and Trejo Valdez, M., Functionality of Aerosol-Gel Deposited TiO2 Thin Films Processed at Low Temperature, J. Sol-Gel Sci. Technol., 2003, vol. 26, nos.1–3, pp. 759–763.
Ryu Dong Hwan, Kim Seong Chul, and Koo Sang Man, Deposition of Titania Nanoparticles on Spherical Silica, J. Sol-Gel Sci. Technol., 2003, vol. 26, nos.1–3, pp. 489–493.
Strizhkov, B.V., Vikhlyantsev, O.F., Pelipas, V.P., and Beskova, E.S., Physicochemical Investigation of Boron-Containing Films Prepared through Hydrolysis of Tetraethoxysilane, Izv. Akad. Nauk SSSR, Neorg. Mater., 1976, vol. 12, no.3, pp. 388–391.
Bernards, T.N.M., Janssen, M.J.C.H., and van Bommel, M.J., Influence of Butanol on the Hydrolysis-Condensation Behaviour of TEOS, J. Non-Cryst. Solids, 1994, vol. 168, pp. 201–212.
Bazhant, V., Khvalovski, V., and Ratouski, I., Silikony. Kremniiorganicheskie soedineniya, ikh poluchenie, svoistva i primenenie (Silicones: Organosilicon Compounds, Their Preparation, Properties, and Applications), Moscow: GNKhL, 1960.
Voznyakovskaya (Shilova), O.A., Men’shikova E.M., Mitnikova I.M., P’yanova L.I., and Chepik, L.F., Investigation into the Influence of the Structure of Boron-Containing Films on the Process of Diffusion of Boron in Silicon, Vopr. Radioelektron., Ser. Tekhnol. Proizv. Oborud., 1984, no. 3, pp. 114–117.
Bubnov, Yu.Z., Chepik, L.F., and Shilova, O.A., Surface Condition of the Boron-Containing Films Prepared from Tetraethoxysilane-Based Solutions as a Function of the Deposition Conditions, in Trudy XVII soveshchaniya “Temperaturoustoichivye funktsional’nye pokrytiya” (Proceedings of the XVII Conference “Heat-Resistant Functional Coatings”), St. Petersburg: OOP NIIKh St. Petersburg Gos. Univ., 1997, vol. 2, pp. 94–97.
Voznyakovskaya (Shilova), O.A., Khairusova L.I., and Chepik, L.F., Development of Solution Compositions by the Techniques of Experimental Design, Vopr. Radioelektron., Ser. Tekhnol. Proizv. Oborud., 1980, no. 3, pp. 61–67.
Shilova, O.A., Moshnikov, V.A., Maximov, A.I., Rumyantseva, A.I., Koscheev, S.V., Bubnov, Yu.Z., and Zhabrev, V.A., Features of Researching Structure and Composition of the Thin Glassy Films Prepared by the Sol-Gel Method, in Proceedings of the International Conference “Science for Materials in the Frontier of Centuries: Advantages and Challenges,” Kiev: IPSM NASU, 2002, vol. 2, pp. 664–665.
Bubnov, Yu.Z., Zhabrev, V.A., Shilova, O.A., Koshcheev, S.V., Maksimov, A.I., and Moshnikov, V.A., Local Analysis of the Catalytic Coatings for Gas-Sensitive Adsorption Sensors in Integrated Design, in Vysokie tekhnologii v promyshlennosti Rossii, Materialy VIII mezhdunarodnoi nauchno-tekhnicheskoi konferentsii (Proceedings of the VIII International Scientific and Technical Conference “High Technologies in Russian Industry”), Moscow: OAO TsNITI “TEKhNOMASh,” 2002, pp. 298–302.
Krakovsky, I., Irakawa, H., Kajiwara, K., and Kohjiya, S., Time Resolved Small Angle X-ray Scattering of Inorganic-Organic Gel Formation Kinetics, J. Non-Cryst. Solids, 1998, vol. 231, pp. 31–40.
Mat\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{e}\)jka, L., Pleštil, J., and Dušek, K., Structure Evolution in Epoxy-Silica Hybrids: Sol-Gel Process, J. Non-Cryst. Solids, 1998, vol. 226, pp. 114–121.
Mat\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{e}\)jka, L., Dukh, O., and Kolarik, J., Reinforcement of Crosslinked Rubbery Epoxies by In-Situ Formed Silica, Polymer, 2000, vol. 41, pp. 1449–1459.
Murav’ev, A.E., Kanunnikova, O.M., Mikhailova, S.S., Shilova, O.A., and Bubnov, Yu.Z., Atomic-Force Microscopic and X-ray Photoelectron Spectroscopic Investigation of the Spin-on-Glass Silicate Films Doped with Manganese, in Temperaturoustoichivye funktsional’nye pokrytiya (Trudy XIX Vserossiiskogo soveshchaniya po temperaturoustoichivym pokrytiyam) [Heat-Resistant Functional Coatings (Proceedings of the XIX Conference on Heat-Resistant Functional Coatings)], St. Petersburg: Yanus, 2003, vol. 2, pp. 46–50.
Muravyev, A.E., Mikhailova, S.S., Shilova, O.A., and Kanunnikova, O.M., AFM Investigation of Pt-Doped Spin-on Glass Thin Silica Films, in Proceedings of the International Conference “Scanning Probe Microscopy,” Nizhni Novgorod: Institute for Physics of Microstructures, Russian Academy of Sciences, 2003, pp. 131–133.
Bubnov, Yu.Z., Vasilenko, T.I., Kozlov, K.V., Krasikov, V.L., Moiseyeva, T.V., Shilova, O.A., and Chepik, L.F., Control of the Gas Microsensitivity by Means of a Catalyst Film Obtained from a Solution, MST-SENSOR TECHNO’93, St. Petersburg, 1993, p. 87.
Shilova, O.A and Bubnov, Yu.Z., Sol-Gel Technology for Preparation of spin-on Glass Films in a Cycle of Manufacturing Gas Sensors, in New Developments on Sensors for Environmental Control (ENVSENS), Siciliano, P., Ed., Singapore: World Scientific, 2003, pp. 90–95.
Bubnov, Yu.Z., Gonchar, I.I., and Shubarev, V.A., Semiconductor Gas Sensors Based on Thin-Film Microelectronic Structures, Radiopromyshlennost’, 2001, no. 2, pp. 8–12.
Bubnov, Yu.Z., Kozlov, K.V., Zabashta, M.A., Shilova, O.A., and Chepik, L.F., Doping of Polysilicon with Phsophorus from Tetraethoxysilane-Based Films, in Trudy XVII soveshchaniya “Temperaturoustoichivye funktsional’nye pokrytiya” (Proceedings of the XVII Conference “Heat-Resistant Functional Coatings”), St. Petersburg: OOP NIIKh St. Petersburg Gos. Univ., 1997, part 2, pp. 88–90.
Shilova, O.A., Bubnov, Yu.Z., and Zhabrev, V.A., Experimental Investigation into Doping SnO2 Gas-Sensitive Resistive Film through Diffusion of Dopants from Spin-on Glass Films, Tezisy dokladov Vserossiiskoi nauchnoi konferentsii “Fizika poluprovodnikov i polumetallov (FPP-2002)” [Abstracts of Papers, All-Russia Scientific Conference “Physics of Semiconductors and Semimetals (PSS-2002)], St. Petersburg: GPU, 2002, pp. 44–46.
Shilova, O.A., Bubnov, Yu.Z., and Zhabrev, V.A., Application of Vitreous Films Prepared by Sol-Gel Method to Doping of Microcrystalline Materials in Manufacturing of Semiconductor Gas Sensors, in Trudy III mezhdunarodnoi konferentsii “Amorfnye i mikrokristallicheskie poluprovodniki” (Proceedings of the III International Conference “Amorphous and Microcrystalline Semiconductors”), St. Petersburg: FTU, 2002, pp. 101–102.
Göpel, W., Hesse, J., and Zemel, J.N., Sensors: A Comprehensive Survey, vol. 1: Fundamentals and General Aspects, Weinheim: VCH, 1989.
Sulz, G., Kühner, G., Peiter, H., Uptmoor, G., Schweizer, W., Low, H., Lacher, M., and Steiner, K., Ni, In, and Sb Implanted Pt and V Catalysed Thin-Film SnO2 Gas Sensors, Sens. Actuators, B, 1993, nos. 15–16, pp. 390–395.
Butta, N., Cinquegrani, L., Migno, E., Tagliente, A., and Pizzini, S.A., Family of Tin-Oxide-Based Sensors with Improved Selectivity to Methane, Sens. Actuators, B, 1992, no. 6, pp. 253–256.
Zhang, J. and Gao, L., Synthesis and Characterization of Antimony-Doped Tin Oxide (ATO) Nanoparticles, Inorg. Chem. Commun., 2004, no. 7, pp. 91–99.
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Original Russian Text Copyright © 2005 by Fizika i Khimiya Stekla, Shilova.
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Shilova, O.A. Silicate nanosized films prepared by the sol-gel method for use in planar technology for fabricating semiconductor gas sensors. Glass Phys Chem 31, 201–218 (2005). https://doi.org/10.1007/s10720-005-0044-6
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DOI: https://doi.org/10.1007/s10720-005-0044-6