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Glass and Ceramics

, Volume 72, Issue 11–12, pp 405–408 | Cite as

Titanium in the Structure of Alkali Borosilicate Glasses

  • V. E. Eremyashev
  • G. G. Korinevskaya
  • S. S. Bukalov
Article

Vibrational spectroscopy is used to show that the effect of adding titanium to K2O–B2O3–SiO2 glasses differing by the ratio of the boron and alkali metal contents is different. This result reflects the change in the structural role of titanium in the glass and is important for evaluating the influence of titanium additions on the properties of alkali borosilicate glass in the process of improving the glassy matrix materials used for the immobilization of radwastes.

Key words

borosilicate glasses spectroscopy structure titanium 

Notes

This work was supported by RFFI grant No. 14-08-00323-a.

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • V. E. Eremyashev
    • 1
    • 2
  • G. G. Korinevskaya
    • 2
  • S. S. Bukalov
    • 3
  1. 1.Southern Ural State UniversityChelyabinskRussia
  2. 2.Institute of MineralogyUral Branch of the Russian Academy of SciencesMiassRussia
  3. 3.Institute of Organometallic CompoundsRussian Academy of SciencesMoscowRussia

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