A transparent glass ceramic, containing lead fluoride β-PbF2 nanocrystals with erbium ions Er3+ (average diameter 8.5 nm), was synthesized by means of secondary thermal treatment of the initial oxyfluoride glass of the system SiO2–GeO2–PbO–PbF2, doped with Er2O3. Its thermal and structural properties, optical absorption, and up-conversion luminescence were studied. The glass ceramic obtained holds promise as a luminophore and makes it possible to obtain intense yellow luminescence by excitation in the IR range of the spectrum.
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References
M. J. Dejneka, “The luminescence and structure of novel transparent oxyfluoride glass-ceramics,” J. Non-Cryst. Solids, 239, 149 – 155 (1998).
M. Takahashi, M. Izuki, R. Kanno, et al., “Up-conversion characteristics of Er3+ in transparent oxyfluoride glass–ceramics,” J. Appl. Phys., 83, 3920 (1998).
P. A. Loiko, G. E. Rachkovskaya, G. B. Zakharevich, and K. V. Yumashev, “New luminescing oxyfluoride glass with europium and ytterbium ions,” Steklo Keram., No. 2, 3 – 6 (2014); P. A. Loiko, G. E. Rachkovskaya, G. B. Zakharevich, and K. V. Yumashev, “New luminescing oxyfluoride glass with europium and ytterbium ions,” Glass Ceram., 71(1 – 2), 41 – 44 (2014).
L. A. Bueno, P. Melnikov, Y. Messaddeq, et al., “Er3+ and Eu3+ containing transparent glass ceramics in the system PbGeO3–PbF2–CdF2,” J. Non-Cryst. Solids, 247, 87 – 91 (1999).
X. Qiao, X. Fan, M. Wang, et al., “Up-conversion luminescence and near infrared luminescence of Er3+ in transparent oxyfluoride glass-ceramics,” Opt. Mater., 27, 597 – 603 (2004).
F. Auzel and P. Goldner, “Towards rare-earth clustering control in doped glasses,” Opt. Mater., 16, 93 – 103 (2001).
Z. Pan, A. Ueda, M. Hay, et al., “Studies of Er3+ doped germinate-oxyfluoride and tellurium-germanate-oxyfluoride transparent glass-ceramics,” J. Non-Cryst. Solids, 352, 801 – 806 (2006).
G. Dantelle, M. Mortier, G. Patriarche, et al., “Er3+-doped PbF2: comparison between nanocrystals in glass-ceramics and bulk single crystals,” J. Solid-State Chem., 179, 1995 – 2003 (2006).
M. Mortier, P. Goldner, C. Chateau, et al., “Erbium doped glassceramics: concentration effect on crystal structure and energy transfer between active ions,” J. Alloys Compound, 323 – 324, 245 – 249 (2001).
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Translated from Steklo i Keramika, No. 8, pp. 6 – 9, August, 2014.
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Rachkovskaya, G.E., Loiko, P.A., Skoptsov, N.A. et al. Yellow Up-Conversion Luminescence of Transparent Glass Ceramics with Erbium Ions. Glass Ceram 71, 266–269 (2014). https://doi.org/10.1007/s10717-014-9666-2
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DOI: https://doi.org/10.1007/s10717-014-9666-2