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Chemically and thermally conjugate synthesis of silicon nitride based compositions using ferrosilicon

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The results of synthesis of composite materials based on silicon nitride, which have been discussed from the standpoint of chemical and (or) thermal conjugation, are presented. Synthesis of silicon nitride via the interaction of ferrosilicon in nitrogen in the combustion regime is examined as the inducing process. It is shown that the energy of self-propagating high-temperature synthesis makes it possible to obtain composite, silicon nitride based, ceramic materials in the process of nitriding ferrosilicon: Si3N4 – ZrO2 – Si2N2O, Si3N4 – TiN – Si2N2O, Si3N4 – BN, Si3Al3O3N5, and Si3N4 – SiC.

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References

  1. N. A. Shilov, On Conjugate Oxidation Reactions [in Russian], Moscow (1905).

  2. A. G. Merzhanov and A. S. Mukas’yan, Solid-Flame Combustion [in Russian], TORUS PRESS, Moscow (2007).

    Google Scholar 

  3. A. G. Merzhanov, “Combustion of condensed systems. New direction of research,” Vestn. Akad. Nauk SSSR, No. 8, 10 – 18 (1979).

  4. L. N. Chukhlomina, Yu. M. Maksimov, O. G. Vitushkina, et al., “Phase composition and morphology of the products of combustion of ferrosilicon in nitrogen,” Steklo Keram., No. 2, 28 – 30 (2007).

  5. L. N. Shukhlomina and Yu. M. Maksimov, “Combustion of Fe – Si alloy in nitrogen gas,” Int. J. Self-Prop. High-Temp. Synth., 16(1), 18 – 22 (2007).

    Article  Google Scholar 

  6. C. D. Jia, Y. Zhou, and C. T. Lei, “Thermal shock resistance of SiC whisker reinforced Si3N4 ceramic composites,” Ceram. Int., 22(2), 107 – 112 (1996).

    Article  CAS  Google Scholar 

  7. G. G. Gnesin, Oxygen-Free Ceramic Materials [in Russian], Tekhnika, Kiev (1987).

    Google Scholar 

  8. H. Kodama, T. Suzuki, H. Sakamoto, and T. Miyoshi, “Toughening of silicon nitride matrix composites by the addition of both silicon carbide particles,” J. Amer. Ceram. Soc., 73(3), 678 – 683 (1990).

    Article  CAS  Google Scholar 

  9. G. L. Khachatryan, A. B. Arutyunyan, and S. L. Kharatyan, “Activated combustion of a silicon – carbon mixture in nitrogen and SHS of composite ceramic powders Si3N4/SiC and silicon carbide,” Fiz. Goren. Vzryva, 42(5), 52 – 62 (2006).

    Google Scholar 

  10. Ch. Agrafiotis, J. Lis, J. A. Puszynski, and V. Hlavacek, “Combustion synthesis of silicon nitride – silicon carbide composites,” J. Amer. Ceram. Soce., 73(11), 1735 – 1738.

  11. L. N. Chukhlomina and Yu. M. Maksimov, “Mechanism of growth of silicon nitride crystals during the combustion of ferrosilicon in nitrogen,” Steklo Keram., No. 8, 18 – 21 (2007).

    Google Scholar 

  12. L. N. Chukhlomina, Yu. M. Maksimov, V. D. Kitler, and O. G. Vitushkin, “On the mechanism and regularities of nitriding of ferrosilicon in a combustion regime,” Fiz. Goren. Vzryva, 42(3), 71 – 78 (2006).

    CAS  Google Scholar 

  13. A. J. Moulson, “Reaction-bonded silicon nitride its formation and properties,” J. Mater. Sci., 14(5), 1017 – 1052.

  14. A. S. Mukas’yan, B. V. Stepanov, Yu. A. Gal’chenko, and I. P. Borovinskaya, “On the mechanism of structure formation of silicon nitride during combustion in nitrogen,” Fiz. Goren. Vzryva, No. 1, 45 – 52 (1990).

  15. N. A. Toropov, V. P. Barzakovskii, V. V. Lapin, and N. N. Kurtseva, Phase Diagrams of Silicate Systems [in Russian], Nauka, Leningrad (1969).

    Google Scholar 

  16. T. Ya. Kosolapova, T. V. Andreeva, T. B. Bartnitskaya, G. G. Gnesin, et al., Non-Metallic Refractory Compounds [in Russian], Metallurgiya, Moscow (1985).

    Google Scholar 

  17. T. V. Vakalova, V. M. Pogrebenkov, and O. A. Chernousova, “Structure – phase transformations during firing of a new ceramic raw material — topaz-containing rock,” Steklo Keram., No. 6, 24 – 27 (2002).

    Google Scholar 

  18. M. I. Gasik, N. P. Lakishev, and B. I. Emlin, Theory and Technology of the Production of Ferroalloys [in Russian], Metallurgiya, Moscow (1988).

    Google Scholar 

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Translated from Steklo i Keramika, No. 8, pp. 21 – 25, August, 2009.

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Chukhlomina, L.N. Chemically and thermally conjugate synthesis of silicon nitride based compositions using ferrosilicon. Glass Ceram 66, 288 (2009). https://doi.org/10.1007/s10717-009-9185-8

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  • DOI: https://doi.org/10.1007/s10717-009-9185-8

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