Thermal Runaway Behavior of Lithium Iron Phosphate Battery During Penetration

Abstract

The nail penetration experiment has become one of the commonly used methods to study the short circuit in lithium-ion battery safety. A series of penetration tests using the stainless steel nail on 18,650 lithium iron phosphate (LiFePO4) batteries under different conditions are conducted in this work. The effects of the states of charge (SOC), penetration positions, penetration depths, penetration speeds and nail diameters on thermal runaway (TR) are investigated. And the accelerating rate calorimeter is applied to reveal the thermal runaway mechanism. The experimental results show that the higher the SOC of the battery, the higher the possibility and risk of TR of the battery, and there seems to be a critical penetration depth where TR occurs. The battery exhibits higher average temperature at higher penetration speeds. Whether the battery get into TR is not related to the penetration speed. When the penetration location near the positive pole and negative pole,the risk of thermal runaway is much higher than the centre position of the battery. The larger the diameter of the nail, the lower the overall temperature of the battery. What’s more, the results of the penetration tests under the condition of parameter coupling shows that the average temperature of battery are greatly affected by the parameters of SOC, penetration position. The temperature of the LiFePO4 battery is within 200°C when the TR occurs induced by the penetration, which is mainly due to the incomplete exothermic reaction inside the battery.

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References

  1. 1.

    Zhu J, Wierzbicki T, Li W (2018) A review of safety-focused mechanical modeling of commercial lithium-ion batteries. J Power Sources 378:153–168

    Article  Google Scholar 

  2. 2.

    An ZJ, Jia L, Ding Y, Dang C, Li XJ (2017) A review on lithium-ion power battery thermal management technologies and thermal safety J Therm Sci 26:391–412

    Article  Google Scholar 

  3. 3.

    Lu LG, Han XB, Li JQ, Hua JF, Ouyang MG (2013) A review on the key issues for lithium-ion battery management in electric vehicles. J Power Sources 226:272–288

    Article  Google Scholar 

  4. 4.

    Tsujikawa T, Yabuta K, Arakawa M, Hayashi K (2013) Safety of large-capacity lithium-ion battery and evaluation of battery system for telecommunications. J Power Sources 244:11–16

    Article  Google Scholar 

  5. 5.

    Abada S, Petit M, Lecocq A, Marlair G, Sauvant-Moynot V, Huet F (2018) Combined experimental and modeling approaches of the thermal runaway of fresh and aged lithium-ion batteries. J Power Sources 399:264–273

    Article  Google Scholar 

  6. 6.

    Ouyang D, Chen M, Liu J, Wei R, Weng J, Wang J (2018) Investigation of a commercial lithium-ion battery under overcharge/over-discharge failure conditions. RSC Adv 8:33414–33424

    Article  Google Scholar 

  7. 7.

    Fernandes Y, Bry A, de Persis S (2018) Identification and quantification of gases emitted during abuse tests by overcharge of a commercial Li-ion battery. J Power Sources 389:106–119

    Article  Google Scholar 

  8. 8.

    Ping P, Wang QS, Huang PF, Sun JH, Chen CH (2014) Thermal behaviour analysis of lithium-ion battery at elevated temperature using deconvolution method. Appl Energy 129:261–273

    Article  Google Scholar 

  9. 9.

    Zhong GB, Li H, Wang C, Xu KQ, Wang QS (2018) Experimental analysis of thermal runaway propagation risk within 18650 lithium-ion battery modules. J Electrochem Soc 165:A1925–A1934

    Article  Google Scholar 

  10. 10.

    Lopez CF, Jeevarajan JA, Mukherjee PP (2015) Experimental analysis of thermal runaway and propagation in lithium-ion battery modules. J Electrochem Soc162:A1905–A1915

    Article  Google Scholar 

  11. 11.

    Huang P, Ping P, Li K, Chen H, Wang Q, Wen J, Sun J (2016) Experimental and modeling analysis of thermal runaway propagation over the large format energy storage battery module with Li4Ti5O12 anode. Appl Energy 183:659–673

    Article  Google Scholar 

  12. 12.

    Mao B, Chen H, Cui Z, Wu T, Wang Q (2018) Failure mechanism of the lithium ion battery during nail penetration. Int J Heat Mass Transf 122:1103–1115

    Article  Google Scholar 

  13. 13.

    Feng X, Sun J, Ouyang M, Wang F, He X, Lu L, Peng H (2015) Characterization of penetration induced thermal runaway propagation process within a large format lithium ion battery module. J Power Sources 275:261–273

    Article  Google Scholar 

  14. 14.

    Lamb J, Orendorff CJ, Steele LAM, Spangler SW (2015) Failure propagation in multi-cell lithium ion batteries. J Power Sources 283:517–523

    Article  Google Scholar 

  15. 15.

    Bugryniec PJ, Davidson JN, Cumming DJ, Brown SF (2019) Pursuing safer batteries: Thermal abuse of LiFePO4 cells. J Power Sources 414:557–568

    Article  Google Scholar 

  16. 16.

    Liu B, Yin S, Xu J (2016) Integrated computation model of lithium-ion battery subject to nail penetration. Appl Energy 183:278–289

    Article  Google Scholar 

  17. 17.

    Kim CS, Yoo JS, Jeong KM, Kim K, Yi CW (2015) Investigation on internal short circuits of lithium polymer batteries with a ceramic-coated separator during nail penetration. Journal of Power Sources 289:41–49

    Article  Google Scholar 

  18. 18.

    Zhao W, Luo G, Wang CY (2015) Modeling nail penetration process in large-format li-ion cells. J Electrochem Soc 162:A207–A217

    Article  Google Scholar 

  19. 19.

    Zhao W, Luo G, Wang C-Y (2015) Modeling Internal shorting process in large-format li-ion cells J Electrochem Soc 162:A1352–A1364

    Article  Google Scholar 

  20. 20.

    Wang QS, Ping P, Zhao XJ, Chu GQ, Sun JH, Chen CH (2012) Thermal runaway caused fire and explosion of lithium ion battery. J Power Sources 208:210–224

    Article  Google Scholar 

  21. 21.

    Santhanagopalan S, Ramadass P, Zhang J (2009) Analysis of internal short-circuit in a lithium ion cell. J Power Sources 194:550–557

    Article  Google Scholar 

  22. 22.

    Chiu KC, Lin CH, Yeh SF, Lin YH, Chen KC (2014) An electrochemical modeling of lithium-ion battery nail penetration. J Power Sources 251:254–263

    Article  Google Scholar 

  23. 23.

    Wu MS, Chiang PCJ, Lin JC, Jan YS (2004) Correlation between electrochemical characteristics and thermal stability of advanced lithium-ion batteries in abuse tests: short-circuit tests. Electrochim Acta 49:1803–1812

    Article  Google Scholar 

  24. 24.

    Roth EP, Doughty DH (2004) Thermal abuse performance of high-power 18650 Li-ion cells. J Power Sources 128:308–318

    Article  Google Scholar 

  25. 25.

    Dubaniewicz TH Jr, DuCarme JP (2014) Further study of the intrinsic safety of internally shorted lithium and lithium-ion cells within methane-air. J Loss Prev Process Ind 32:165–173

    Article  Google Scholar 

  26. 26.

    Liu BH, Zhao H, Yu HL, Li J, Xu J (2017) Multiphysics computational framework for cylindrical lithium-ion batteries under mechanical abusive loading. Electrochim Acta 256:172–184

    Article  Google Scholar 

  27. 27.

    Liu BH, Jia YK, Li J, Yin S, Yuan CH, Hu ZH, Wang LB, Li YX, Xu J (2018) Safety issues caused by internal short circuits in lithium-ion batteries. J Mater Chem A 6:21475–21484

    Article  Google Scholar 

  28. 28.

    Maleki H, Howard JN (2009) Internal short circuit in Li-ion cells J Power Sources 191:568–574

    Article  Google Scholar 

  29. 29.

    Wang SR, Lu LL, Liu XJ (2013) A simulation on safety of LiFePO4/C cell using electrochemical-thermal coupling model. J Power Sources 244:101–108

    Article  Google Scholar 

  30. 30.

    Perea A, Paolella A, Dube J, Champagne D, Mauger A, Zaghib K (2018) State of charge influence on thermal reactions and abuse tests in commercial lithium-ion cells. J Power Sources 399:392–397

    Article  Google Scholar 

  31. 31.

    Zavalis TG, Behm M, Lindbergh G (2012) Investigation of short-circuit scenarios in a lithium-ion battery cell. J Electrochem Soc 159:A848–A859

    Article  Google Scholar 

  32. 32.

    Feng XN, Lu LG, Ouyang MG, Li JQ, He XM (2016) A 3D thermal runaway propagation model for a large format lithium ion battery module. Energy 115:194–208

    Article  Google Scholar 

  33. 33.

    Kim GH, Pesaran A, Spotnitz R (2007) A three-dimensional thermal abuse model for lithium-ion cells. J Power Sources 170:476–489

    Article  Google Scholar 

  34. 34.

    Spotnitz R, Franklin J (2003) Abuse behavior of high-power, lithium-ion cells. J Power Sources 113:81–100

    Article  Google Scholar 

  35. 35.

    Bryden TS, Dimitrov B, Hilton G, de Leon CP, Bugryniec P, Brown S, Cumming D, Cruden A (2018) Methodology to determine the heat capacity of lithium-ion cells. J Power Sources 395:369–378

    Article  Google Scholar 

  36. 36.

    Wang QS, Sun JH, Yao XL, Chen CH (2005) Thermal stability of LiPF6/EC+DEC electrolyte with charged electrodes for lithium ion batteries. Thermochimica Acta 437:12–16

    Article  Google Scholar 

  37. 37.

    Kawamura T, Kimura A, Egashira M, Okada S, Yamaki JI (2002) Thermal stability of alkyl carbonate mixed-solvent electrolytes for lithium ion cells. J Power Sources 104:260–264

    Article  Google Scholar 

Download references

Acknowledgements

This work is supported by the National Key R&D Program of China (No. 2016YFB0100306), the National Natural Science Foundation of China (Nos. 51674228 and 51976209), and the Fundamental Research Funds for the Central Universities (No. WK2320000044). Dr. Q.S Wang is supported by Youth Innovation Promotion Association CAS (No. 2013286).

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Correspondence to Qingsong Wang.

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Huang, Z., Li, H., Mei, W. et al. Thermal Runaway Behavior of Lithium Iron Phosphate Battery During Penetration. Fire Technol 56, 2405–2426 (2020). https://doi.org/10.1007/s10694-020-00967-1

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Keywords

  • Lithium-ion batteries safety
  • Thermal runaway
  • Nail penetration
  • Critical depth
  • Short circuit