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X-Ray Structure and PMR Spectra of Polycaproamide Modified by a Polyfluorinated Alcohol

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Fibre Chemistry Aims and scope

Effects on polycaproamide structure of a polyfluorinated alcohol immobilized on montmorillonite clay nanoparticles were studied using x-ray structure analysis and broad-line PMR spectroscopy. An exfoliated composite formed and caused the crystal and molecular structures of this heterochain polymer to reorganize. A composite based on the polyfluorinated alcohol changed the mobility of macromolecular chain segments and increased the fraction of planar trans-conformations.

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Authors and Affiliations

  1. Volgograd State Technical University, Volgograd, Russia

    S. V. Kudashev & V. F. Zheltobryukhov

  2. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Ekaterinburg, Russia

    N. A. Zhuravlev & T. A. Denisova

  3. V. A. Belyi Metal-Polymer Research Institute, National Academy of Sciences of Belarus, Gomel, Belarus

    V. M. Shapovalov

  4. Gomel State Medical University, Homieĺ, Belarus

    A. M. Valenkov

Authors
  1. S. V. Kudashev
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  2. N. A. Zhuravlev
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  3. V. M. Shapovalov
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  4. T. A. Denisova
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  5. A. M. Valenkov
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  6. V. F. Zheltobryukhov
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Corresponding author

Correspondence to S. V. Kudashev.

Additional information

Translated from Khimicheskie Volokna, No. 1, pp. 10-14, January—February, 2019.

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Kudashev, S.V., Zhuravlev, N.A., Shapovalov, V.M. et al. X-Ray Structure and PMR Spectra of Polycaproamide Modified by a Polyfluorinated Alcohol. Fibre Chem 51, 9–13 (2019). https://doi.org/10.1007/s10692-019-10037-0

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  • DOI: https://doi.org/10.1007/s10692-019-10037-0

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