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Environmental Monitoring and Assessment

, Volume 185, Issue 6, pp 4933–4941 | Cite as

SPME-based air sampling method for inhalation exposure assessment studies: case study on perchlorethylene exposure in dry cleaning

  • Mohammad Javad Zare Sakhvidi
  • Abdul Rahman Bahrami
  • Alireza Ghiasvand
  • Hossein Mahjub
  • Ludovic Tuduri
Article

Abstract

Exposure to perchlorethylene, especially for dry cleaning workers and for people living near dry cleaning shops, could lead to several diseases and disorders. This study examines the value of solid-phase microextraction (SPME) for sampling perchlorethylene in the atmosphere of dry cleaning shops. Carboxen/polydimethylsiloxane (CAR/PDMS) in 0.5-cm retracted mode was selected. There were no significant differences between sampling rates at different temperatures (range of 20 to 30 °C) and air velocities (2 to 50 cm/s). On the opposite, relative humidity (RH) had a significant effect on sampling rates. Method reproducibility was realized in the laboratory and field conditions and was 6.2 % and 7 to 11 %, respectively. Repeatability was also determined as 8.9 %. Comparison of the results according to the American Industrial Hygiene Association exposure assessment strategy showed the SPME sampler yields more conservative results in comparison with traditional standard method.

Keywords

Perchlorethylene Air sampling Solid-phase microextraction Exposure assessment 

References

  1. Amagai, T., & Matsushita, H. (1999). A passive sampler-GC/ECD method for analyzing 18 volatile organohalogen compounds in indoor and outdoor air and its application to a survey on indoor pollution in Shizuoka, Japan. Talanta, 50(4), 851–863.CrossRefGoogle Scholar
  2. Baldwin, P. E. J., & Maynard, A. D. (1998). A survey of wind speeds in indoor workplaces. Annals of Occupational Hygiene, 42(5), 303–313.Google Scholar
  3. Bullock, W. H., & Ignacio. J. S. (2006). A strategy for assessing and managing occupational exposures. American Industrial Hygiene Association.Google Scholar
  4. Chen, Y. (2004). New calibration approaches in solid phase microextraction for on-site analysis. PhD thesis, University of Waterloo.Google Scholar
  5. Chen, C. Y., Hsiech, C., & Lin, J. M. (2006). Diffusive sampling of methylene chloride with solid phase microextraction. Journal of Chromatography. A, 1137(2), 138–144.CrossRefGoogle Scholar
  6. Damiano, J., & Mulhausen, J. (1999). A strategy for assessing and managing occupational exposures. Fairfax: American Industrial Hygiene Association.Google Scholar
  7. Earnest, G. S. (2002). A control technology evaluation of state-of-the-art, perchloroethylene dry-cleaning machines. Applied Occupational and Environmental Hygiene, 17(5), 352–359.CrossRefGoogle Scholar
  8. Eller, P. M., & Cassinelli, M. E. (1994). NIOSH manual of analytical methods. Darby: Diane.Google Scholar
  9. Emara, A. M., Abo El-Noor, M. M., Hassan, N. A., & Wagih, A. A. (2010). Immunotoxicity and hematotoxicity induced by tetrachloroethylene in egyptian dry cleaning workers. Inhalation Toxicology, 22(2), 117–124.CrossRefGoogle Scholar
  10. Fuller, E. N., Schettler, P. D., & Giddings, J. C. (1966). New method for prediction of binary gas-phase diffusion coefficients. Industrial and Engineering Chemistry, 58(5), 18–27.CrossRefGoogle Scholar
  11. Haberhauer Troyer, C., Rosenberg, E., & Grasserbauer, M. (1999). Evaluation of solid–phase microextraction for sampling of volatile organic sulfur compounds in air for subsequent gas chromatographic analysis with atomic emission detection. Journal of Chromatography. A, 848(1), 305–315.CrossRefGoogle Scholar
  12. Koziel, J., Jia, M., Khaled, A., Noah, J., & Pawliszyn, J. (1999). Field air analysis with SPME device. Analytica Chimica Acta, 400(1–3), 153–162.CrossRefGoogle Scholar
  13. Koziel, J., Jia, M., & Pawliszyn, J. (2000). Air sampling with porous solid-phase microextraction fibers. Analytical Chemistry, 72(21), 5178–5186.CrossRefGoogle Scholar
  14. Lee, I., & Tsai, S. W. (2008). Passive sampling of ambient ozone by solid phase microextraction with on-fiber derivatization. Analytica Chimica Acta, 610(2), 149–155.CrossRefGoogle Scholar
  15. Lynge, E., Andersen, A., Rylander, L., Tinnerberg, H., Lindbohm, M. L., Pukkala, E., et al. (2006). Cancer in persons working in dry cleaning in the Nordic countries. Environmental Health Perspectives, 114(2), 213–219.CrossRefGoogle Scholar
  16. NTP. (2011). Report on carcinogens (12th ed., p. 499). Research Triangle Park, NC: U.S. Department of Health and Human Services, Public Health Service, National Toxicology Program.Google Scholar
  17. OSHA. (1999). Sampling and analytical methods: Tetrachloroethylene trichloroethylene. In. http://www.osha.gov/dts/sltc/methods/mdt/mdt1001/1001.html. Access date: 09/11/2011.
  18. OSHA. (2005). Reducing worker exposure to perchloroethylene (PERC) in dry cleaning. In. http://www.osha.gov/Publications/osha3253.pdf. Access date: 09/11/2011.
  19. Risticevic, S., Lord, H., Górecki, T., Arthur, C. L., & Pawliszyn, J. (2010). Protocol for solid-phase microextraction method development. Nature Protocols, 5(1), 122–139.CrossRefGoogle Scholar
  20. Thompson, K. M., & Evans, J. S. (1997). The value of improved national exposure information for perchloroethylene (perc): A case study for dry cleaners. Risk Analysis, 17(2), 253–271.CrossRefGoogle Scholar
  21. Tuduri, L., Desauziers, V., & Fanlo, J. L. (2001). Potential of solid-phase microextraction fibers for the analysis of volatile organic compounds in air. Journal of Chromatographic Science, 39(12), 521–529.CrossRefGoogle Scholar
  22. U.S. Environmental protection agency. (1994). Chemical summary for perchloroethylene. Office of Pollution Prevention and Toxics, EPA 749-f-94-020a.Google Scholar
  23. Wang, J., Tuduri, L., Mercury, M., Millet, M., Briand, O., & Montury, M. (2009). Sampling atmospheric pesticides with SPME: Laboratory developments and field study. Environmental Pollution, 157(2), 365–370.CrossRefGoogle Scholar
  24. Zare Sakhvidi, M. J., Bahrami, A. R., Afkhami, A., & Rafiei, A. (2011). Development of diffusive solid phase microextraction method for sampling of epichlorohydrin in air. International Journal of Environmental Analytical Chemistry. doi: 10.1080/03067319.2011.620704.
  25. Zare Sakhvidi, M. J., Bahrami, A. R., Ghiasvand, A., Mahjub, H., & Tuduri, L. (2011). Field application of SPME as a novel tool for occupational exposure assessment with inhalational anesthetics. Environmental Monitoring and Assessment, 1–8. doi: 10.1007/s10661-011-2434-7.
  26. Zare Sakhvidi, M. J., Bahrami, A. R., Ghiasvand, A., Mahjub, H., & Tuduri, L. (2012). Determination of inhalational anesthetics in field and laboratory by SPME GC/MS. Analytical Letters, 45(4), 375–385.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2012

Authors and Affiliations

  • Mohammad Javad Zare Sakhvidi
    • 1
  • Abdul Rahman Bahrami
    • 2
  • Alireza Ghiasvand
    • 3
  • Hossein Mahjub
    • 4
  • Ludovic Tuduri
    • 5
  1. 1.Department of Occupational Health, Faculty of HealthShahid Sadoughi University of Medical SciencesYazdIran
  2. 2.Department of Occupational Health, Research Centre for Health Sciences, School of Public HealthHamedan University of Medical ScienceHamedanIran
  3. 3.Department of Chemistry, Faculty of ScienceLorestan UniversityKhoramabadIran
  4. 4.Department of Biostatistics and Epidemiology, Research Centre for Health Sciences, School of Public HealthHamedan University of Medical ScienceHamedanIran
  5. 5.LPTC-Institut des Sciences MoléculairesPérigueux CedexFrance

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