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Environmental Monitoring and Assessment

, Volume 185, Issue 2, pp 1737–1754 | Cite as

Sorbed metals fractionation and risk assessment of release in river sediment and particulate matter

  • M. Saeedi
  • L. Y. Li
  • A. R. Karbassi
  • A. J. Zanjani
Article

Abstract

Fractionation of metals in natural sediment and suspended particulate matter (SPM) of Tadjan River is investigated. Competitive sorption, sorption capacities of sediment and SPM as well as fractionation of metal-loaded sediment and SPM are also examined. A risk assessment code (RAC) is applied to estimate the risk of heavy metals release into the environment during the sorption process. Results revealed that sediments and SPM containing more than 25 % of clay minerals and higher amounts of calcite have great capacity of metal sorption, particularly for Cu, Ni, and Mn. Assessing the risk of metals release prior to and following sorption tests indicates that RAC of metals would significantly increase from the level of no or low risk in natural sediment and SPM to high or very high risk after sorption. The Langmuir model reveals that the highest affinity for Cu, Mn, and Ni in sediment is the organic fraction. The classic isotherm models of Freundlich and Langmuir can fit the data from chemical extraction studies of adsorbed metals, indicating that although sorption was apparently a physical and chemical process in the river, isotherm models can be used to simulate the sorption and accumulation in different geochemical phases within the particulate matter.

Keywords

Heavy metals Risk assessment Sediment Tadjan River Fractionation Sorption 

Notes

Acknowledgment

This research has been financially supported by Iran National Science Foundation (INSF).

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Copyright information

© Springer Science+Business Media B.V. 2012

Authors and Affiliations

  • M. Saeedi
    • 1
    • 2
  • L. Y. Li
    • 2
  • A. R. Karbassi
    • 3
  • A. J. Zanjani
    • 4
  1. 1.Enviro-hydroinformatics Center of Excellence, School of Civil EngineeringIran University of Science and TechnologyTehranIran
  2. 2.Department of Civil EngineeringThe University of British ColumbiaVancouverCanada
  3. 3.Faculty of EnvironmentUniversity of TehranTehranIran
  4. 4.Department of Water and Environmental Engineering, School of Civil EngineeringIran University of Science and TechnologyTehranIran

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