Environmental Monitoring and Assessment

, Volume 177, Issue 1–4, pp 151–163 | Cite as

A novel environmental indicator for monitoring of pesticides

  • Federico Luchi
  • Valeria Vigni
  • Riccardo Basosi
  • Elena Busi


The identification of an indicator for monitoring pesticides is a very effective analytical approach because it allows one to schedule and simplify the analytical routine. In this study, a new indicator has been designed, which has to be able to define a scale of priorities in the pesticides monitoring. A starting equation was developed involving the escaping tendency of a given substance from a phase (based on the Mackay model I level). The reliability of the indicator was tested by application to a model system, consisting of a defined and limited area, choosing water as matrix over a period of 6 years. A group of marker compounds was also defined to implement the predictive efficacy of the indicator. The results obtained by modeling were compared to those obtained by experimentation of the same model system. The indicator was subsequently and appropriately modified creating a new equation, including a kinetic factor, which considers the environmental degradation processes. The effect of the rectified indicator was consistent with the sales data list of compounds, when applied to the markers. The indicator developed in this study, tested as a model on specific area-phase-period (Province of Siena, water phase, 2000–2006), is applicable to any other area-phase-period, adjusting the partition value of the Mackay model for the case under study.


Environmental indicator Pesticides monitoring Model system Multi-residual approach 


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  1. Bacci, E. (1992). Ecotoxicology of organic contaminants. London: Lewis.Google Scholar
  2. Borroni, M. (2007). WIN-BDF BANCA DATI FITOFARMACI computer package, service pack 4 for Microsoft Windows NT, Prod. Ecospi s.r.l. Milano, Distrib. Ed. “L’informatore Agrario”, Verona.Google Scholar
  3. Businelli, M. (1991). Il controllo degli inquinamenti in agricoltura; gli inquinanti organici. In Chimica del suolo. P.Sequi coord. Bologna: Patron.Google Scholar
  4. CHEMFINDER (2000). Scientific Database Gateway.
  5. Chiou, C. T., Schmedding, D. W., & Manes, M. (1982). Partitioning of organic compound in octanol-water systems. Environmental Science & Technology, 16, 4–10.CrossRefGoogle Scholar
  6. CPCN (2009). Compendium-Of-Pesticide-Common-Names.
  7. CRPV (2009). Centro Ricerche Produzioni Vegetali—Archivio, Fitofarmaci.
  8. EPA (2005). USA Environmental Protection Agency. Document: EPA/600/R-05/053 Method 535. Measurement of chloroacetanilide and other acetamide herbicide degradates in drinking water by solid phase extraction and liquid chromatography/tandem mass spectrometry (LC/MS/MS), version 1.1, April 2005, J.A. Shoemaker, M.V. Bassett.Google Scholar
  10. FITOGEST (2009). Il motore di ricerca dei fitosanitari.
  11. Mackay, D. (1979). Finding fugacity feasible. Environmental Science and Technology, 13(10), 1218–1223.CrossRefGoogle Scholar
  12. Mackay, D. (1982). Fugacity revisited. Environmental Science & Technology, 16, 654A–660A.CrossRefGoogle Scholar
  13. Mackay, D., & Paterson, S. (1981). Calculating fugacity. Environmental Science & Technology, 15, 1006–1014.CrossRefGoogle Scholar
  14. Miller, G. T., Jr. (1994). Living in the environment: Principles, connections, and solutions. Belmont: Wadsworth.Google Scholar
  16. PAN (2009). PAN Pesticides Database.
  17. REACH (2006). (Registration, Evaluation Authorisation and Restriction of Chemical substances) Official Journal of the European Union. Parliament and council regulation (ec) no. 1907/2006 (corrigendum 29 may 2007) and directive 2006/121/ec (Corrigendum 29 May 2007), = oj:l:2006:396:0001:0849:en:pdf.
  18. Sicbaldi, F., Sarra, A., & Copeta, G. L. (1997). Diatomaceous earth-assisted extraction for the multiresidue determination of pesticides. Journal of Chromatography A, 765, 23–30.CrossRefGoogle Scholar
  19. Tomlin, C. (1994). The pesticid manual. UK: Crop Protection.Google Scholar

Copyright information

© Springer Science+Business Media B.V. 2010

Authors and Affiliations

  • Federico Luchi
    • 1
    • 3
  • Valeria Vigni
    • 2
  • Riccardo Basosi
    • 1
  • Elena Busi
    • 1
  1. 1.Department of ChemistryUniversity of SienaSienaItaly
  2. 2.Department of SienaARPAT (Agenzia regionale Protezione Ambientale)SienaItaly
  3. 3.Laboratorio di Sanità Pubblica Area Vasta Nord-Ovest ToscanaLuccaItaly

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