Environmental Monitoring and Assessment

, Volume 100, Issue 1–3, pp 201–216 | Cite as

Air monitoring of persistent organic pollutants in the Great Lakes: IADN vs. AEOLOS

  • Matt F. Simcik


When designing a monitoring campaign, one has to consider many factors in the decision to perform a long-term synoptic monitoring program or a short-term intensive study. Each has its own advantages and disadvantages. This paper compares and contrasts the information obtained from two studies conducted on the Laurentian Great Lakes. One, the Integrated Atmospheric Deposition Network (IADN), is a long-term synoptic monitoring study and the other, the Atmospheric Exchange Over Lakes and Oceans (AEOLOS), was a short-term intensive study. The advantages of long-term synoptic monitoring programs are providing greater spatial information, the relative influence of long and short-range transport on the regional background, gross loadings representative of the majority of each lake and long-term temporal trends. Short-term intensive studies provide more information on the processes governing sources, transport and deposition, such as the urban/industrial influence on adjacent large water bodies, specific sources to an urban/industrial area and short-term fluctuations in concentrations due to meteorology, source strength and photochemical reactions. Using information provided by both the IADN and AEOLOS studies, areas of urban influence are predicted for each of the five Great Lakes.


atmospheric loadings POPs source apportionment spatial coverage temporal trends 


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  1. Buehler, S. S., Basu, I., Hites, R. A. 2001A comparison of PAH, PCB, and pesticide concentrations in air at two rural sites on Lake SuperiorEnviron. Sci. Technol.3524172422Google Scholar
  2. Buehler, S. S., Hites, R. A. 2002The Great Lakes’ integrated atmospheric deposition networkEnviron. Sci. Technol.36354A359AGoogle Scholar
  3. Caffrey, P. F., Ondov, J. M., Zufall, M. J., Davidson, C. I. 1998Determination of size-dependent dry particle deposition velocities with multiple intrinsic elemental tracersEnviron. Sci. Technol.3216151622Google Scholar
  4. Cortes, D. R., Basu, I., Sweet, C. W., Brice, K. A., Hoff, R. M., Hites, R. A. 1998Temporal trends in gas-phase concentrations of chlorinated pesticides measured at the shores of the Great LakesEnviron. Sci. Technol.3219201927Google Scholar
  5. Cortes, D. R., Basu, I., Sweet, C. W., Hites, R. A. 2000Temporal trends in and influence of wind on PAH concentrations measured near the Great LakesEnviron. Sci. Technol.34356360Google Scholar
  6. Cortes, D. R., Hites, R. A. 2000Detection of statistically significant trends in atmospheric concentrations of semivolatile compoundsEnviron. Sci. Technol.3428262829Google Scholar
  7. Dzubay, T. G., Stevens, R. K., Gordon, G. E., Olmez, I., Sheffield, A. E., Courtney, W. J. A. 1988Composite receptor method applied to Philadelphia aerosolEnviron. Sci. Technol.224652Google Scholar
  8. Franz, T. P., Eisenreich, S. J., Holsen, T. M. 1998Dry deposition of particulate polychlorinated biphenyls and polycyclic aromatic hydrocarbons to Lake MichiganEnviron. Sci. Technol.3236813688Google Scholar
  9. Green, M. L., DePinto, J. V., Sweet, C., Hornbuckle, K. C. 2000Regional spatial and temporal interpolation of atmospheric PCBs: Interpretation of LakeMichigan mass balance dataEnviron. Sci. Technol.3418331841Google Scholar
  10. Hillery, B. R., Basu, I., Sweet, C. W., Hites, R. A. 1997Temporal and spatial trends in a long-term study of gas-phase PCB concentrations near the Great LakesEnviron. Sci. Technol.3118111816Google Scholar
  11. Hillery, B. R., Simcik, M. F., Basu, I., Hoff, R. M., Strachan, W. M. J., Burniston, D., Chan, C. H., Brice, K. A., Sweet, C. W., Hites, R. A. 1998Atmospheric deposition of toxic pollutants to the Great Lakes as measured by the integrated atmospheric deposition networkEnviron. Sci. Technol.3222162221Google Scholar
  12. Hoff, R. M., Strachan, W. M. J., Sweet, C. W., Chan, C. H., Shackleton, M., Bidleman, T. F., Brice, K. A., Burniston, D. A., Cussion, S., Gatz, D. F., Harlin, K., Schroeder, W. H. 1996Atmospheric deposition of toxic chemicals to the Great Lakes: A review of data through 1994Atmos. Environ.3035053527Google Scholar
  13. Hoff, R. M., Brice, K. A., Halsall, C. J. 1998Nonlinearity in the slopes of Clausius-Clapeyron plots for SVOCsEnviron. Sci. Technol.3217931798Google Scholar
  14. Hsu, Y.-K., Holsen, T. M., Hopke, P. K. 2003Locating and quantifying PCB sources in Chicago: Receptor modeling and field samplingEnviron. Sci. Technol.37681690Google Scholar
  15. Kao, A. S., Friedlander, S. K. 1995Frequency distributions of PM10 chemical components and their sourcesEnviron. Sci. Technol.291928Google Scholar
  16. Kleinman, M. T., Pasternack, B. S., Eisenbud, M., Kneip, T. J. 1980Identifying and estimating the relative importance of sources of airborne particulatesEnviron. Sci. Technol.146265Google Scholar
  17. Kowalczyk, G. S., Gordon, G. E. and Rheingrover, S. W.: 1982, ‘Identification of atmospheric particulate sources in washington, D.C., using chemical element balances’, Environ. Sci. Technol. 16.Google Scholar
  18. Landis, M. S., Keeler, G. J. 2002Atmospheric mercury deposition to Lake Michigan during the Lake Michigan mass balance studyEnviron. Sci. Technol.3645184524Google Scholar
  19. Landis, M. S., Vette, A. F., Keeler, G. J. 2002Atmospheric mercury in the Lake Michigan basin: Influence of the Chicago/Gary urban areaEnviron. Sci. Technol.3645084517Google Scholar
  20. Lewis, C. W., Baumgardner, R. E., Stevens, R. K., Russwurm, G. M. 1986Receptor modeling study of Denver winter hazeEnviron. Sci. Technol.2011261136Google Scholar
  21. Morandi, M. T., Daisey, J. M., Lioy, P. J. 1987Development of a modified factor analysis/ multiple regression model to apportion suspended particulate matter in a complex urban airshedAtmos. Environ.2118211831Google Scholar
  22. Offenberg, J. H., Baker, J. E. 1997Polychlorinated biphenyls in Chicago precipitation: Enhanced wet deposition to near-shore Lake MichiganEnviron. Sci. Technol.3115341538Google Scholar
  23. Offenberg, J. H., Baker, J. E. 2002Precipitation scavenging of polychlorinated biphenyls and polycyclic aromatic hydrocarbons along an urban to over-water transectEnviron. Sci. Technol.3637633771Google Scholar
  24. Paode, R. D., Sofuoglu, S. C., Sivadechathep, J., Noll, K. E., Holsen, T. M., Keeler, G. J. 1998Dry deposition fluxes and mass size distributions of Pb, Cu, and Zn measured in Southern Lake Michigan during AEOLOSEnviron. Sci. Technol.3216291635Google Scholar
  25. Paode, R. D., Shahin, U. M., Sivadechathep, J., Holsen, T. M., Franek, W. J. 1999Source apportionment of dry deposited and airborne coarse particles collected in the Chicago areaEnviron. Sci. Technol.31473486Google Scholar
  26. Pratsinis, S. E., Zeldin, M. D., Ellis, E. C. 1988Source resolution of the fine carbonaceous aerosol by principal component - Stepwise regression analysisEnviron. Sci. Technol.22212216Google Scholar
  27. Simcik, M. F., Zhang, H., Eisenreich, S., Franz, T. P. 1997Urban contamination of the Chicago/Coastal Lake Michigan atmosphere by PCBs and PAHs during AEOLOSEnviron. Sci. Technol.3121412147Google Scholar
  28. Simcik, M. F., Basu, I., Sweet, C. W., Hites, R. A. 1999Temperature dependence and temporal trends of polychlorinated biphenyl congeners in the Great Lakes atmosphereEnviron. Sci. Technol.3319911995Google Scholar
  29. Simcik, M. F., Eisenreich, S. J., Lioy, P. J. 1999Source apportionment and source/sink relationships of PAHs in the coastal atmosphere of Chicago and Lake MichiganAtmos. Environ.3350715079Google Scholar
  30. Simcik, M. F., Hoff, R. M., Strachan, W. M. J., Sweet, C. W., Basu, I., Hites, R. A. 2000Temporal trends of semivolatile organic contaminants in Great Lakes precipitationEnviron. Sci. Technol.34361367Google Scholar
  31. Simcik, M. F., Jeremiason, J. D., Lipiatou, E., Eisenreich, S. J. 2003Enhanced removal of hydrophobic organic contaminants by settling sediments in western Lake SuperiorJ. Great Lakes Res.294153CrossRefGoogle Scholar
  32. Sofuoglu, S. C., Holsen, T. M. 1997Dry deposition fluxes and mass size distributions of trace elements measured near southern Lake MichiganEnviron. Res. Forum7–8691696Google Scholar
  33. Sofuoglu, S. C., Paode, R. D., Sivadechathep, J., Noll, K. E., Holsen, T. M., Keeler, G. J. 1998Dry deposition fluxes and atmospheric size distributions of mass, Al, and Mg measured in southern Lake Michigan during AEOLOSEnviron. Sci. Technol.29281293Google Scholar
  34. Tuncel, S. G., Olmez, I., Parrington, J. R., Gordon, G. E., Stevens, R. K. 1985Composition of fine particle regional sulfate component in Shenandoah ValleyEnviron. Sci. Technol.19529537Google Scholar
  35. Wania, F., Haugen, J.-E., Lei, Y. D., Mackay, D. 1998Temperature dependence of atmospheric concentrations of semivolatile organic compoundsEnviron. Sci. Technol.3210131021Google Scholar
  36. Zhang, H.: 1996. Enhanced Air-Water Exchange of Polychlorinated Biphenyls in Southern Lake Michigan in the Chicago Plume. Master of Science. Civil Engineering, Universtiy of Minnesota.Google Scholar
  37. Zhang, H., Eisenreich, S. J., Franz, T. R., Baker, J. E., Offenberg, J. H. 1999Evidence for increased gaseous PCB fluxes to Lake Michigan from ChicagoEnviron. Sci. Technol.3321292137Google Scholar
  38. Zufall, M. J., Davidson, C. I., Caffrey, P. F., Ondov, J. M. 1998Airborne concentrations and dry deposition fluxes of particulate species to surrogate surfaces deployed in southern Lake MichiganEnviron. Sci. Technol.3216231628Google Scholar

Copyright information

© Springer 2005

Authors and Affiliations

  • Matt F. Simcik
    • 1
  1. 1.Division of Environmental & Occupational Health, School of Public HealthUniversity of MinnesotaMinneapolisUSA

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