Oxidative potential (OP) and mineralogy of iron ore particulate matter at the Gol-E-Gohar Mining and Industrial Facility (Iran)

  • Naghmeh Soltani
  • Behnam Keshavarzi
  • Armin Sorooshian
  • Farid Moore
  • Christina Dunster
  • Ana Oliete Dominguez
  • Frank J. Kelly
  • Prakash Dhakal
  • Mohamad Reza Ahmadi
  • Sina Asadi
Original Paper

Abstract

Concentrations of total suspended particulate matter, particulate matter with aerodynamic diameter <2.5 μm (PM2.5), particulate matter <10 μm (PM10), and fallout dust were measured at the Iranian Gol-E-Gohar Mining and Industrial Facility. Samples were characterized in terms of mineralogy, morphology, and oxidative potential. Results show that indoor samples exceeded the 24-h PM2.5 and PM10 mass concentration limits (35 and 150 µg m−3, respectively) set by the US National Ambient Air Quality Standards. Calcite, magnetite, tremolite, pyrite, talc, and clay minerals such as kaolinite, vermiculite, and illite are the major phases of the iron ore PM. Accessory minerals are quartz, dolomite, hematite, actinolite, biotite, albite, nimite, laumontite, diopside, and muscovite. The scanning electron microscope structure of fibrous-elongated minerals revealed individual fibers in the range of 1.5 nm to 71.65 µm in length and 0.2 nm to 3.7 µm in diameter. The presence of minerals related to respiratory diseases, such as talc, crystalline silica, and needle-shaped minerals like amphibole asbestos (tremolite and actinolite), strongly suggests the need for detailed health-based studies in the region. The particulate samples show low to medium oxidative potential per unit of mass, in relation to an urban road side control, being more reactive with ascorbate than with glutathione or urate. However, the PM oxidative potential per volume of air is exceptionally high, confirming that the workers are exposed to a considerable oxidative environment. PM released by iron ore mining and processing activities should be considered a potential health risk to the mine workers and nearby employees, and strategies to combat the issue are suggested.

Keywords

Particulate matter Amphibole asbestos Oxidative potential Iron ore Mining 

Notes

Acknowledgements

This work was financially supported by Gol-E-Gohar mining and industrial company. The authors wish to thank Shiraz University Research Committee and medical geology research center of Shiraz University for supporting this research. AS acknowledges support from Grant 2 P42 ES04940 from the National Institute of Environmental Health Sciences (NIEHS) Superfund Research Program, NIH and the Center for Environmentally Sustainable Mining through the TRIF Water Sustainability Program at the University of Arizona. The University Spectroscopy and Imaging Facility (USIF) at the University of Arizona is acknowledged for assistance with SEM/EDX analysis.

Supplementary material

10653_2017_9926_MOESM1_ESM.docx (1.2 mb)
Supplementary material 1 (DOCX 1131 kb)

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Copyright information

© Springer Science+Business Media Dordrecht 2017

Authors and Affiliations

  • Naghmeh Soltani
    • 1
  • Behnam Keshavarzi
    • 1
  • Armin Sorooshian
    • 2
    • 3
  • Farid Moore
    • 1
  • Christina Dunster
    • 4
  • Ana Oliete Dominguez
    • 4
  • Frank J. Kelly
    • 4
  • Prakash Dhakal
    • 5
  • Mohamad Reza Ahmadi
    • 6
  • Sina Asadi
    • 1
  1. 1.Department of Earth Sciences, College of ScienceShiraz UniversityShirazIran
  2. 2.Department of Chemical and Environmental EngineeringUniversity of ArizonaTucsonUSA
  3. 3.Department of Hydrology and Atmospheric SciencesUniversity of ArizonaTucsonUSA
  4. 4.MRC-PHE Centre for Environment and HealthKing’s College LondonLondonUK
  5. 5.Department of Soil, Water and Environmental ScienceUniversity of ArizonaTucsonUSA
  6. 6.Gol-E-Gohar Iron Ore and Steel Research InstituteGol-E-Gohar Mining and Industrial Co.SirjanIran

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