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6-Oxocorumdephine and 18-methoxyeladine, new norditerpene alkaloids from the aerial part of Delphinium uralense

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Chemistry of Natural Compounds Aims and scope

The new norditerpene alkaloids 6-oxocorumdephine and 18-methoxyeladine were isolated from the aerial part of Delphinium uralense N. The structures 16β-hydroxy-7,8-methylenedioxy-6-oxo-1α,14α,18-trimethoxy-N-ethylaconitane and 6β,16β-dihydroxy-7,8-methylenedioxy-1 α,14 α,18-trimethoxy-N-ethylaconitane were proposed based on PMR, 13C NMR, IR, and mass spectra.

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Acknowledgment

The work was supported financially by a grant of the RF President (for support of leading scientific schools, No. NSh-4434.2006.3), a grant of the RFBR No. 08-03-90265-Uzb, and the Program for Basic Research of the RAS Presidium “Development of Methods for Preparing Chemical Compounds and Creating New Materials,” Project 8P.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Russian Federation, 450054 Ufa, prosp. Oktyabrya, 71, Russia

    T. M. Gabbasov, E. M. Tsyrlina, L. V. Spirikhin & M. S. Yunusov

  2. Institute of Biology, Ufa Scientific Center, Russian Academy of Sciences, Russian Federation, 450054 Ufa, prosp. Oktyabrya, 71, Russia

    N. I. Fedorov

Authors
  1. T. M. Gabbasov
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  2. E. M. Tsyrlina
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  3. L. V. Spirikhin
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  4. N. I. Fedorov
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  5. M. S. Yunusov
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Correspondence to T. M. Gabbasov.

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Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 603-605, November-December, 2008.

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Gabbasov, T.M., Tsyrlina, E.M., Spirikhin, L.V. et al. 6-Oxocorumdephine and 18-methoxyeladine, new norditerpene alkaloids from the aerial part of Delphinium uralense . Chem Nat Compd 44, 745–748 (2008). https://doi.org/10.1007/s10600-009-9184-6

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  • DOI: https://doi.org/10.1007/s10600-009-9184-6

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