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Cationic ring contraction of seven-membered cycle of 3,4-dihydro-2H-1,5-benzoxathiepine derivatives

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Chemistry of Heterocyclic Compounds Aims and scope

A number of 1,4-benzoxathiine derivatives was obtained using ring contraction of seven-membered cycle of 3,4-dihydro-2H-1,5-benzoxathiepin-3-ol derivatives. This synthetic approach allowed to obtain the corresponding alkene, alcohol, nitrile, chloride, bromide, azide, and amine.

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Authors and Affiliations

  1. Department of Organic Chemistry, Kyiv Taras Shevchenko National University, 12 Lva Tolstoho St, Kyiv, 01601, Ukraine

    Taras M. Tarasiuk, Lyudmila M. Potikha & Yulian M. Volovenko

  2. Enamine Ltd., 78 Chervonotkatska St, Kyiv, 02660, Ukraine

    Taras M. Tarasiuk & Olena O. Shyshkina

Authors
  1. Taras M. Tarasiuk
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  2. Olena O. Shyshkina
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  3. Lyudmila M. Potikha
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  4. Yulian M. Volovenko
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Corresponding author

Correspondence to Taras M. Tarasiuk.

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Published in Khimiya Geterotsiklicheskikh Soedinenii, 2019, 55(4/5), 416–420

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Tarasiuk, T.M., Shyshkina, O.O., Potikha, L.M. et al. Cationic ring contraction of seven-membered cycle of 3,4-dihydro-2H-1,5-benzoxathiepine derivatives. Chem Heterocycl Comp 55, 416–420 (2019). https://doi.org/10.1007/s10593-019-02474-w

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  • DOI: https://doi.org/10.1007/s10593-019-02474-w

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