The rearrangements of substituted 5H-chromeno[2,3-b]pyridines in basic medium are described. Such reactions proceed via ANRORC mechanism and rotation of pyridine ring, resulting in the formation of 1,6-naphthyridine derivatives in high yields.
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The study was performed with financial support from the Russian Foundation for Basic Research (project No. 16-33-00909 mol_a).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2017, 53(9), 1050–1052
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Alekseeva, A.Y., Bardasov, I.N., Malyshkina, N.L. et al. Rearrangement of 3-cyano-5H-chromeno[2,3-b]pyridines to 1,6-naphthyridine derivatives. Chem Heterocycl Comp 53, 1050–1052 (2017). https://doi.org/10.1007/s10593-017-2168-8
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DOI: https://doi.org/10.1007/s10593-017-2168-8