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Electrophilic heterocyclization reactions of allylamino- and propargylamino-substituted sym-tetrazines in the presence of HgI2

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Chemistry of Heterocyclic Compounds Aims and scope

A range of 3-azolyl-6-methylimidazo[1,2-b][1, 2, 4, 5]tetrazines was obtained for the first time by electrophilic heterocyclization of 6-allylamino-3-azolyl- and 3-azolyl-6-propargylamino-1,2,4,5-tetrazines in the presence of HgI2. The structures of the starting materials and final products were confirmed by 1H and 13C NMR spectroscopy, elemental analysis, and X-ray structural analysis.

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Authors and Affiliations

  1. I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 S. Kovalevskoi / 20 Akademicheskaya St., Yekaterinburg, 620990, Russia

    Rashida I. Ishmetova, Irina A. Belyaninova, Nina K. Ignatenko, Pavel A. Slepukhin, Gennady L. Rusinov & Valery N. Charushin

  2. Ural Federal University named after the first President of Russia B. N. Yeltsin, 19 Mir St., Yekaterinburg, 620002, Russia

    Rashida I. Ishmetova, Pavel A. Slepukhin, Gennady L. Rusinov & Valery N. Charushin

Authors
  1. Rashida I. Ishmetova
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  2. Irina A. Belyaninova
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  3. Nina K. Ignatenko
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  4. Pavel A. Slepukhin
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  5. Gennady L. Rusinov
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  6. Valery N. Charushin
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Corresponding author

Correspondence to Pavel A. Slepukhin.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2017, 53(2), 213–218

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Ishmetova, R.I., Belyaninova, I.A., Ignatenko, N.K. et al. Electrophilic heterocyclization reactions of allylamino- and propargylamino-substituted sym-tetrazines in the presence of HgI2 . Chem Heterocycl Comp 53, 213–218 (2017). https://doi.org/10.1007/s10593-017-2042-8

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  • DOI: https://doi.org/10.1007/s10593-017-2042-8

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