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Molecular Necklaces Composed of Tetraazamacrocyclic and Crown Ether Building Blocks

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Chemistry of Heterocyclic Compounds Aims and scope

A series of catenanes was synthesized via self-assembly of dibenzo-24-crown-8, ethylenediamine, and either three, four, or five cyclidene units coordinating nickel(II) or copper(II) ions. A number of molecular necklaces were successfully isolated and characterized. ESI mass spectrometry proved to be the most useful analytical tool to establish the exact composition of synthesized catenanes. Additionally, single crystal of a grand macrocycle composed of four tetraazamacrocyclic units complexing copper(II) ions was obtained and its X-ray structure has been successfully determined.

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Financial support from the National Centre of Science in Poland (NCN, Grant OPUS No. 2014/13/B/ST5/03727) is gratefully acknowledged.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Polish Academy of Sciences, ul. M. Kasprzaka 44/52, 01-224, Warszawa, Poland

    Iwona Mames, Jarosław Kowalski, Paweł Świder & Bohdan Korybut-Daszkiewicz

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  1. Iwona Mames
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  2. Jarosław Kowalski
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  3. Paweł Świder
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  4. Bohdan Korybut-Daszkiewicz
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Corresponding author

Correspondence to Bohdan Korybut-Daszkiewicz.

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Published in Khimiya Geterotsiklicheskikh Soedinenii, 2017, 53(1), 87–91

I. Mames and J. Kowalski contributed equally.

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Mames, I., Kowalski, J., Świder, P. et al. Molecular Necklaces Composed of Tetraazamacrocyclic and Crown Ether Building Blocks. Chem Heterocycl Comp 53, 87–91 (2017). https://doi.org/10.1007/s10593-017-2025-9

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  • DOI: https://doi.org/10.1007/s10593-017-2025-9

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