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Microwave-assisted synthesis of 4-(2,2'-bithiophen-5-yl)-5-phenylpyrimidine derivatives as sensors for detection of nitroaromatic explosives

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Chemistry of Heterocyclic Compounds Aims and scope

A reaction sequence involving microwave-assisted Suzuki cross-coupling steps and bromination with N-bromosuccinimide was used to synthesize 4-{4-[4',5'-bis(4-diphenylaminophenyl)-3'-hexyl-2,2'-bithiophen-5-yl]pyrimidin-5-yl}benzonitrile. The optical properties of the obtained compound were studied to evaluate it for possible applications as a sensor of nitroaromatic compounds in acetonitrile solutions and gas phase.

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This work was supported by a grant from the Russian Science Foundation (project No. 16-13-10435).

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Authors and Affiliations

  1. I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, 22 S. Kovalevskoi/20 Akademicheskaya, Yekaterinburg, 620990, Russia

    Egor V. Verbitskiy, Ekaterina M. Cheprakova, Gennady L. Rusinov, Oleg N. Chupakhin & Valery N. Charushin

  2. Ural Federal University named after the First President of Russia B. N. Yeltsin, 19 Mira St., Yekaterinburg, 620002, Russia

    Egor V. Verbitskiy, Anna A. Baranova, Konstantin O. Khokhlov, Kseniya I. Lugovik, Gennady L. Rusinov, Oleg N. Chupakhin & Valery N. Charushin

Authors
  1. Egor V. Verbitskiy
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  2. Ekaterina M. Cheprakova
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  3. Anna A. Baranova
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  4. Konstantin O. Khokhlov
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  5. Kseniya I. Lugovik
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  6. Gennady L. Rusinov
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  7. Oleg N. Chupakhin
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  8. Valery N. Charushin
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Corresponding author

Correspondence to Egor V. Verbitskiy.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2016, 52(11), 904–909

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Verbitskiy, E.V., Cheprakova, E.M., Baranova, A.A. et al. Microwave-assisted synthesis of 4-(2,2'-bithiophen-5-yl)-5-phenylpyrimidine derivatives as sensors for detection of nitroaromatic explosives. Chem Heterocycl Comp 52, 904–909 (2016). https://doi.org/10.1007/s10593-017-1984-1

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  • DOI: https://doi.org/10.1007/s10593-017-1984-1

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