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Synthesis of Dithiaza- and Dioxadithiazacycloalkanes by Cyclothiomethylation of Arylamines with Formaldehyde and α,ω-Dithiols

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Chemistry of Heterocyclic Compounds Aims and scope

New derivatives of 1,5,3-dithiazepanes and macroheterocycles were synthesized by a three-component cyclothiomethylation of arylamines with formaldehyde and α,ω-dithiols. The sorption properties of 3-phenyl-1,5,3-dithiazepane and 6-phenyl-1,11-dioxa-4,8-dithia-6-azacyclotridecane applicable for the extraction of Ag(I) and Pd(II) ions from nitric acid solutions at room temperature were studied by a static method.

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This work was performed with financial support from the Russian Foundation for Basic Research (projects No. 14-03-00240-a, No. 14-03-97023-r_Povolzhye_a) and the Ministry of Education and Science of the Russian Federation (grant NSh-6651.2016.3).

The structural studies of compounds were performed at the Collective Usage Center " Agidel" at the Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Oktyabrya Ave., Ufa, 450075, Russia

    Guzel R. Khabibullina, Ekaterina S. Fedotova, Ekaterina S. Meshcheryakova, Vnira R. Akhmetova & Askhat G. Ibragimov

  2. M. V. Lomonosov Institute of Fine Chemical Technologies, Moscow Technological University, 78 Vernadskogo Ave., Moscow, 119454, Russia

    Tatyana M. Buslaeva

Authors
  1. Guzel R. Khabibullina
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  2. Ekaterina S. Fedotova
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  3. Ekaterina S. Meshcheryakova
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  4. Tatyana M. Buslaeva
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  5. Vnira R. Akhmetova
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  6. Askhat G. Ibragimov
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Correspondence to Guzel R. Khabibullina.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2016, 52(10), 840–848

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Khabibullina, G.R., Fedotova, E.S., Meshcheryakova, E.S. et al. Synthesis of Dithiaza- and Dioxadithiazacycloalkanes by Cyclothiomethylation of Arylamines with Formaldehyde and α,ω-Dithiols. Chem Heterocycl Comp 52, 840–848 (2016). https://doi.org/10.1007/s10593-016-1975-7

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  • DOI: https://doi.org/10.1007/s10593-016-1975-7

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