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Chemistry of Heterocyclic Compounds

, Volume 52, Issue 8, pp 546–550 | Cite as

Anisyl-, aminophenyl-, and naphthylmethylsilatranes revisited

  • Yu Wang
  • Vitalijs RomanovsEmail author
  • Jana Spura
  • Lubova Ignatovica
  • Thierry Roisnel
  • Viatcheslav JouikovEmail author
Article

Three Si-substituted silatranes were synthesized in order to rectify their structure with particular attention to the length of the N–Si intramolecular dative bond. DFT calculations of potential energy profile as a function of the N–Si distance and the structure of HOMO were considered. The latter was found to vary its localization depending on the electron-donating properties of the substituent and the N–Si distance.

Keywords

silatranes DFT calculations N–Si dative bond synthesis X-ray structure 

Notes

The authors gratefully acknowledge the support of this research by InnovaBalt program and the Latvian Council for Science (Project 225/2012).

Supplementary material

10593_2016_1928_MOESM1_ESM.pdf (242 kb)
ESM 1 (PDF 241 kb)

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Yu Wang
    • 1
  • Vitalijs Romanovs
    • 2
    Email author
  • Jana Spura
    • 2
  • Lubova Ignatovica
    • 2
  • Thierry Roisnel
    • 1
  • Viatcheslav Jouikov
    • 1
    Email author
  1. 1.UMR 6226 ISCRUniversity of Rennes IRennesFrance
  2. 2.Latvian Institute of Organic SynthesisRigaLatvia

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