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Chemistry of Heterocyclic Compounds

, Volume 51, Issue 6, pp 563–567 | Cite as

Microwave-Assisted Synthesis of Novel Perimidinium Salts as N-Heterocyclic Carbene Precursors: Involvement in Palladium-Catalyzed Cross-Coupling Reactions

  • Gulnihan Onar
  • Mert Olgun Karatas
  • Bülent Alici
  • Engin Cetinkaya
Article

In the current study, five novel perimidinium chlorides were synthesized in good yields by reaction of 1-(3-methylbenzyl)perimidine with five different alkyl chlorides under microwave irradiation in 30 minutes. Synthesized compounds were characterized by IR, 1H, 13C NMR spectroscopic methods and elemental analyses. Performance of in situ formed catalytic system which consist of the perimidinium salts and Pd(OAc)2 was investigated for Heck and Suzuki reactions in aqueous media, and desired products were obtained in good yields.

Keyword

carbenes palladium perimidine catalysis Heck reaction microwave irradiation Suzuki reaction 

Supplementary material

10593_2015_1732_MOESM1_ESM.pdf (645 kb)
ESM 1 (PDF 644 kb)

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Gulnihan Onar
    • 1
  • Mert Olgun Karatas
    • 1
  • Bülent Alici
    • 1
  • Engin Cetinkaya
    • 2
  1. 1.Department of Chemistry, Faculty of Arts and SciencesInonu UniversityMalatyaTurkey
  2. 2.Department of Chemistry, Faculty of SciencesEge UniversityIzmirTurkey

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