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Chemistry of Heterocyclic Compounds

, Volume 50, Issue 11, pp 1559–1566 | Cite as

Synthesis and Structure of Phosphanylated Bis-Triazoles as Potential Ligands for Chiral Catalysts

  • A. A. Kirilchuk
  • A. A. Yurchenko
  • Yu. G. Vlasenko
  • A. N. Kostyuk
  • A. B. Rozhenko
Article

Potential atropisomeric ligands, diphenylphosphane derivatives of bis-triazoles, were synthesized by direct phosphanylation of the starting bis-triazoles with chlorodiphenylphosphane. Their crystal structure was elucidated by X-ray diffractional analysis. The conformations of these compounds were modeled by DFT calculations.

Keywords

BINAP 1,2,4-triazole phosphanes atropisomerism DFT X-ray structural analysis 

Notes

The authors are grateful to Prof. Uwe Manthe and Dr. Thorsten Tönsing of Bielefeld University, Germany, for providing access to computer cluster and GAUSSIAN-03 and TURBOMOLE software, as well as for technical support of calculations.

Supplementary material

10593_2014_1624_MOESM1_ESM.pdf (627 kb)
ESM 1 (PDF 627 kb)

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • A. A. Kirilchuk
    • 1
  • A. A. Yurchenko
    • 1
  • Yu. G. Vlasenko
    • 1
  • A. N. Kostyuk
    • 1
  • A. B. Rozhenko
    • 1
    • 2
  1. 1.Institute of Organic ChemistryNational Academy of Sciences of UkraineKyivUkraine
  2. 2.Bielefeld UniversityBielefeldGermany

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