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Synthesis of 2-Nitro-1H-Benzo[f]Chromenes

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Chemistry of Heterocyclic Compounds Aims and scope

The reaction of Mannich bases derived from 2-naphthol with 4-(2-nitrovinyl)morpholine or N,N-di-methyl(2-nitrovinyl)amine in acetic anhydride gives 2-nitro-1H-benzo[f]chromenes. This reaction may be regarded formally as the addition of a push-pull olefin acting as a 1,2-ambiphile with naphthalenic o-quinone methide acting as a 1,4-ambiphilic reagent.

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This work was carried out with the financial support from the Ministry of Education and Science of the Russian Federation within the framework of the baseline of the State Assignment for scientific activity No. 2014/199 using the scientific equipment at the Samara State Technical University Collective Use Center "Physicochemical Investigation of Substances and Materials"

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Authors and Affiliations

  1. Samara State Technical University, 244 Molodogvardeiskaya St., Samara, 443100, Russia

    V. A. Osyanin, A. V. Lukashenko, D. V. Osipov & Yu. N. Klimochkin

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  1. V. A. Osyanin
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  2. A. V. Lukashenko
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  3. D. V. Osipov
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  4. Yu. N. Klimochkin
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Correspondence to V. A. Osyanin.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1663–1668, November, 2014.

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Osyanin, V.A., Lukashenko, A.V., Osipov, D.V. et al. Synthesis of 2-Nitro-1H-Benzo[f]Chromenes. Chem Heterocycl Comp 50, 1528–1533 (2015). https://doi.org/10.1007/s10593-014-1620-2

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  • DOI: https://doi.org/10.1007/s10593-014-1620-2

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