Chemistry of Heterocyclic Compounds

, Volume 50, Issue 9, pp 1259–1269 | Cite as

Synthesis of Several Substituted Pyridine-3-Sulfonyl Chlorides, -Sulfonic Acids, and -Sulfonyl Amides*

  • L. V. Dyadyuchenko
  • I. G. Dmitrieva
  • D. Yu. Nazarenko
  • V. D. Strelkov

Diazotation of substituted 3-aminopyridines with subsequent substitution of diazo groups with sulfonyl groups in the obtained diazonium chlorides was used to synthesize the corresponding pyridine-3-sulfonyl chlorides. The conditions for this synthesis were optimized by taking into account the detailed understanding of this substitution. The synthesized pyridine-3-sulfonyl chlorides were converted to pyridine-3-sulfonic acids and -sulfonyl amides.


sulfonic acids sulfonyl amides sulfonyl chlorides diazotation elimination substitution side reactions 


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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • L. V. Dyadyuchenko
    • 1
  • I. G. Dmitrieva
    • 2
  • D. Yu. Nazarenko
    • 1
  • V. D. Strelkov
    • 1
  1. 1.All-Russian Research Institute of Biological Plant ProtectionKrasnodarRussia
  2. 2.Kuban State Agricultural UniversityKrasnodarRussia

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