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Synthesis of Diastereomeric Spirocyclic Nitroxyl Radicals of 3-Imidazoline Series with Two Mesogenic Groups

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Chemistry of Heterocyclic Compounds Aims and scope

Alkylaromatic α-hydroxylamino ketones with a p-hydroxy(alkoxy)aryl substituent were used for the preparation of stable diastereomeric spirocyclic nitroxyl radicals of 3-imidazoline series, having two different or identical mesogenic groups in the molecule. The molecular structure of these compounds was determined by NMR study of their diamagnetic reduced derivatives.

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This work was done owing financial support from the Russian Foundation for Basic Research – JSPS (Japanese Society for the Promotion of Science) (project No.11-03-92107-YaF-а), Integration program of the Siberian Branch, Russian Academy of Sciences (Cooperative Basic Research, project No. 1), and the Ministry of Education and Science of the Russian Federation (contract 8456).

The spectral investigations, elemental analysis, and differential scanning calorimetry were performed at the Certified Testing Analytical Center of the Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences (Novosibirsk).

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Authors and Affiliations

  1. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk, 630090, Russia

    E. V. Zaitseva, A. V. Shernyukov, S. A. Amitina, I. A. Grigor’ev & D. G. Mazhukin

  2. Graduate School of Human and Environmental Studies, University of Kyoto, Sakyo-ku, Yoshida Nihonmatsu-cho, Kyoto, 606-8501, Japan

    R. Tamura

  3. Novosibirsk State University, 2 Pirogova St., Novosibirsk, 630090, Russia

    D. G. Mazhukin

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  1. E. V. Zaitseva
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  2. A. V. Shernyukov
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  3. S. A. Amitina
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  4. R. Tamura
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  5. I. A. Grigor’ev
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  6. D. G. Mazhukin
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Correspondence to E. V. Zaitseva.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1207-1220, August, 2014.

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Zaitseva, E.V., Shernyukov, A.V., Amitina, S.A. et al. Synthesis of Diastereomeric Spirocyclic Nitroxyl Radicals of 3-Imidazoline Series with Two Mesogenic Groups. Chem Heterocycl Comp 50, 1113–1125 (2014). https://doi.org/10.1007/s10593-014-1571-7

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  • DOI: https://doi.org/10.1007/s10593-014-1571-7

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