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Reaction of Enamines and Azaenamines Containing a Thioamide Group with Dimethyl Acetylenedicarboxylate

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Chemistry of Heterocyclic Compounds Aims and scope

The reaction between enamines and azaenamines containing a thioamide group and dimethyl acetylenedicarboxylate was studied under various conditions. It was shown that exchanging one of the carbon atoms in the structure of the investigated compounds for a nitrogen atom significantly affected the reactivity. Functionalized thiopyrans and thiazolidinones were obtained during this investigation.

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Notes

  1. Here and further in the Experimental the 13С NMR signals of major isomers in the isomeric mixtures are marked with an asterix.

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Authors and Affiliations

  1. Ural Federal University named after the First President of Russia B. N. Yeltsin, 19 Mir St., Yekaterinburg, 620002, Russia

    N. P. Belskaya, K. I. Lugovik, A. D. Ivina & V. A. Bakulev

  2. State Key Laboratory of Elemento-organic Chemistry, Nankai University, 94 Weijin Rd., Tianjin, 300071, P. R. China

    Z. J. Fan

Authors
  1. N. P. Belskaya
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  2. K. I. Lugovik
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  3. A. D. Ivina
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  4. V. A. Bakulev
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  5. Z. J. Fan
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Correspondence to N. P. Belskaya.

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 962-975, June, 2014.

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Belskaya, N.P., Lugovik, K.I., Ivina, A.D. et al. Reaction of Enamines and Azaenamines Containing a Thioamide Group with Dimethyl Acetylenedicarboxylate. Chem Heterocycl Comp 50, 888–900 (2014). https://doi.org/10.1007/s10593-014-1543-y

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  • DOI: https://doi.org/10.1007/s10593-014-1543-y

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