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Synthesis and Structure of a New Polydentate 8-Hydroxyquinoline Ligand System with a 1,3-Tropolone Fragment at Position 2 in the Quinoline Ring

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Chemistry of Heterocyclic Compounds Aims and scope

An original three-step method has been developed for the synthesis of a new polydentate 8-hydroxyquinoline ligand system with a 1,3-tropolone fragment at position 2 of the quinoline ring. X-ray diffraction structural analysis, 1H and 13C NMR spectroscopy, and quantum-chemical calculations showed that this ligand exists in the NH-tautomeric form with the phenolic hydroxyl group in the exo position of the quinoline ring.

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This work was carried out with the financial support of the Russian Foundation for Basic Research (grant 12-03-00179a), Program of the Materials Science Division of the Russian Academy of Sciences (OKh-1), and the Grants Council of the President of the Russian Federation (grant NSh-274.2014.3).

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Authors and Affiliations

  1. Southern Scientific Center, Russian Academy of Sciences, 41 Chekhov St., Rostov-on-Don, 344006, Russia

    I. E. Mikhailov, A. A. Kolodina, G. A. Dushenko & Yu. A. Sayapin

  2. Southern Federal University, 7 Zorge St., Rostov-on-Don, 344090, Russia

    I. E. Mikhailov, Yu. M. Artyushkina & V. V. Tkachev

  3. Scientific-Research Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 Stachki Ave., Rostov-on-Don, 344090, Russia

    G. A. Dushenko & V. I. Minkin

  4. Institute of Problems of Chemical Physics, 1 Akademika Semenova Ave., Chernogolovka, 142432, Russia

    S. M. Aldoshin

Authors
  1. I. E. Mikhailov
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  2. A. A. Kolodina
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  3. G. A. Dushenko
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  4. Yu. M. Artyushkina
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  5. V. V. Tkachev
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  6. S. M. Aldoshin
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  7. Yu. A. Sayapin
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  8. V. I. Minkin
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Correspondence to I. E. Mikhailov.

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 897-907, June, 2014.

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Mikhailov, I.E., Kolodina, A.A., Dushenko, G.A. et al. Synthesis and Structure of a New Polydentate 8-Hydroxyquinoline Ligand System with a 1,3-Tropolone Fragment at Position 2 in the Quinoline Ring. Chem Heterocycl Comp 50, 828–837 (2014). https://doi.org/10.1007/s10593-014-1537-9

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  • DOI: https://doi.org/10.1007/s10593-014-1537-9

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