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Chemistry of Heterocyclic Compounds

, Volume 50, Issue 5, pp 720–725 | Cite as

Synthesis of N-Hydroxyalkyl-1,5,3-Dithiazepanes Based on Amino Alcohols

  • E. B. Rakhimova
  • R. A. Ismagilov
  • E. S. Meshcheryakova
  • R. A. Zainullin
  • L. M. Khalilov
  • A. G. Ibragimov
  • U. M. Dzhemilev
Article

Catalytic methods were developed for the synthesis of N-hydroxyalkyl-1,5,3-dithiazepanes by recyclization of 1-oxa-3,6-dithiacycloheptane with amino alcohols and by intermolecular cyclization of 1,2-ethanedithiol with methoxymethylamino alcohols.

Keywords

amino alcohols 1,2-ethanedithiol N-hydroxyalkyl-1,5,3-dithiazepanes methoxymethyl-amino alcohols heterocyclization catalysis recyclization 

Notes

This work received financial support from the Russian Foundation for Basic Research (grants 13-03-12027 ofi_m, 14-03-00240-а, 14-03-97023-r_povolzhye_а), and NSh-2136.2014.3.

The authors would like to express their gratitude to V. A. Veklov from the laboratory of catalyst preparation, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, for the contribution of heterogeneous catalysts.

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • E. B. Rakhimova
    • 1
  • R. A. Ismagilov
    • 2
  • E. S. Meshcheryakova
    • 1
  • R. A. Zainullin
    • 2
  • L. M. Khalilov
    • 1
  • A. G. Ibragimov
    • 1
  • U. M. Dzhemilev
    • 1
  1. 1.Institute of Petrochemistry and CatalysisRussian Academy of SciencesUfaRussia
  2. 2.Ufa State University of Economics and ServicesUfaRussia

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