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Chemistry of Heterocyclic Compounds

, Volume 49, Issue 12, pp 1815–1820 | Cite as

Photo- and Thermochromic Spirans 40*. Spiropyrans based on 5-Benzoxazolyl-4-Hydroxyisophthalic Aldehyde

  • N. A. Voloshin
  • A. V. ChernyshevEmail author
  • E. V. Solov’eva
  • K. E. Shepelenko
  • A. V. Metelitsa
  • V. I. Minkin
Article

Formylation of 2-(2-hydroxyphenyl)benzoxazole gave 5-benzoxazolyl-substituted 4-hydroxyisophthalic aldehyde, which served as a precursor to the synthesis of novel photochromic spiro[indoline-benzopyrans] containing a benzoxazole group at position 8 of the benzopyran moiety. The obtained compounds possess photochromic properties in solution.

Keywords

benzoxazole hydroxyisophthalic aldehyde merocyanines spiropyrans photochromism 

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • N. A. Voloshin
    • 1
  • A. V. Chernyshev
    • 2
    Email author
  • E. V. Solov’eva
    • 2
  • K. E. Shepelenko
    • 2
  • A. V. Metelitsa
    • 2
  • V. I. Minkin
    • 1
    • 2
  1. 1.Southern Scientific Centerthe Russian Academy of SciencesRostov-on-the-DonRussia
  2. 2.Scientific-Research Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-the-DonRussia

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