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Chemistry of Heterocyclic Compounds

, Volume 49, Issue 12, pp 1732–1739 | Cite as

Nano Sulfated Titania as a Heterogeneous Solid Acid Catalyst for the Synthesis of Pyrroles by Clauson–Kaas Condensation under Solvent-free Conditions

  • M. Hosseini-SarvariEmail author
  • S. Najafvand-Derikvandi
  • A. Jarrahpour
  • R. Heiran
Article

A new and environmentally benign method for the preparation of N-substituted pyrroles from one-pot condensation reaction of 2,5-dimethoxytetrahydrofuran with amines and diamines in the presence of nano sulfated titania under solvent-free conditions is presented. This new protocol features simple operation, easy availability, stability, and eco-friendliness of catalyst, as well as high to excellent yields of products. In addition, we report for the first time an alternative method for the synthesis of pyrroles from aromatic amines containing the β-lactam fragment using nano sulfated titania as catalyst.

Keywords

2,5-dimethoxytetrahydrofuran nano sulfated titania N-substituted pyrroles Clauson-Kaas condensation 

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • M. Hosseini-Sarvari
    • 1
    Email author
  • S. Najafvand-Derikvandi
    • 1
  • A. Jarrahpour
    • 1
  • R. Heiran
    • 1
  1. 1.Department of ChemistryShiraz UniversityShirazI. R. Iran

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