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Chemistry of Heterocyclic Compounds

, Volume 49, Issue 11, pp 1579–1588 | Cite as

Correlation of the Homo–Lumo Gap in Furyl and Thienyl Nitrones and Nitroethenes with their Electrochemical Redox Potentials*

  • M. Boulkroune
  • L. IgnatovichEmail author
  • V. Muravenko
  • J. Spura
  • A. Chibani
  • V. JouikovEmail author
Article

Two series of potentially biologically active heteroaryl derivatives of nitrones and nitroethenes have been prepared and studied by cyclic voltammetry and DFT modeling. Satisfactory correlations of experimental first peak potentials E p , both in oxidation and in reduction, with the energies of the corresponding frontier orbitals were found.

Keywords

organylsilylfuryl(thienyl)nitroethenes organylsilylfuryl(thienyl)nitrones IR 11329Si NMR spectroscopy electrochemical redox potentials synthesis 

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  1. 1.Department of ChemistryUniversity MentouriConstantineAlgeria
  2. 2.Latvian Institute of Organic SynthesisRigaLatvia
  3. 3.UMR 6226 CPMUniversity of Rennes 1RennesFrance

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