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Cyclization of the Molecular Ions of N-[2-(Cyclopent-1-en-1-yl)phenyl]arylamides upon Electron Impact

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Chemistry of Heterocyclic Compounds Aims and scope

Analysis of the electron impact mass spectra, collision-induced dissociation spectra, and high-resolution mass spectrometry data of N-[2-(cyclopent-1-en-1-yl)phenyl]arylamides and isomeric 2-arylspiro[3,1-benzoxazine-4,1'-cyclopentanes] indicated that only a small portion of the molecular ions of the arylamides undergo cyclization to give the corresponding substituted 3,1-benzoxazines prior fragmentation. The donor-acceptor properties of the benzene ring substituents affect the efficiency of cyclization of the molecular ions.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Science Center, Russian Academy of Sciences, 71 Oktyabrya, Ufa, 450054, Russia

    E. G. Galkin, A. S. Erastov, E. M. Vyrypaev, I. I. Furlei, I. B. Abdrakhmanov & Sh. M. Salikhov

  2. Ufa State Petroleum Technology University, 1 Kosmonavtov St., Ufa, 450062, Russia

    S. A. Kras’ko

Authors
  1. E. G. Galkin
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  2. A. S. Erastov
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  3. E. M. Vyrypaev
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  4. I. I. Furlei
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  5. I. B. Abdrakhmanov
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  6. Sh. M. Salikhov
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  7. S. A. Kras’ko
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Corresponding author

Correspondence to A. S. Erastov.

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 1160-1165, July, 2013.

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Galkin, E.G., Erastov, A.S., Vyrypaev, E.M. et al. Cyclization of the Molecular Ions of N-[2-(Cyclopent-1-en-1-yl)phenyl]arylamides upon Electron Impact. Chem Heterocycl Comp 49, 1082–1086 (2013). https://doi.org/10.1007/s10593-013-1346-6

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  • DOI: https://doi.org/10.1007/s10593-013-1346-6

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