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Synthesis and properties of triethylammonium 4-aryl(hetaryl)-3,5-dicyano-6-oxo-1,4,5,6-tetrahydro-pyridine-2-selenolates

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Chemistry of Heterocyclic Compounds Aims and scope

The reaction of (hetero)aromatic aldehydes, cyanoselenoacetamide, and 1-(cyanoacetyl)-3,5-dimethyl-pyrazole in the presence of triethylamine gives a mixture of the cis and trans diastereomers of triethylammonium 4-aryl(hetaryl)-3,5-dicyano-6-oxo-1,4,5,6-tetrahydropyridine-2-selenolates. The selenolates obtained react with alkyl halides to form the corresponding selenides.

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Authors and Affiliations

  1. “ChemEx” Laboratory, Vladimir Dal, East-Ukrainian National University, 20a/7 Molodezhny Kv., Lugansk, 91034, Ukraine

    K. A. Frolov, V. V. Dotsenko & S. G. Krivokolysko

  2. N. D. Zelinsky Institute of Organic Chemistry, 47 Leninsky Ave., Moscow, 117913, Russia

    V. P. Litvinov

Authors
  1. K. A. Frolov
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  2. V. V. Dotsenko
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  3. S. G. Krivokolysko
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  4. V. P. Litvinov
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Correspondence to K. A. Frolov.

Additional information

V. P. Litvinov (Deceased).

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 471-477, March, 2012.

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Frolov, K.A., Dotsenko, V.V., Krivokolysko, S.G. et al. Synthesis and properties of triethylammonium 4-aryl(hetaryl)-3,5-dicyano-6-oxo-1,4,5,6-tetrahydro-pyridine-2-selenolates. Chem Heterocycl Comp 48, 442–447 (2012). https://doi.org/10.1007/s10593-012-1012-4

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  • DOI: https://doi.org/10.1007/s10593-012-1012-4

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