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Chemistry of Heterocyclic Compounds

, Volume 47, Issue 12, pp 1551–1560 | Cite as

Heterocyclic carbene complexes of nickel, palladium, and copper(I) as effective catalysts for the reduction of ketones*

  • N. I. KorotkikhEmail author
  • V. Sh. Saberov
  • A. V. Kiselev
  • N. V. Glinyanaya
  • K. A. Marichev
  • T. M. Pekhtereva
  • G. V. Dudarenko
  • N. A. Bumagin
  • O. P. Shvaika
Article

Carbene complexes of nickel, palladium, and copper(I) effectively catalyze the reduction of aromatic ketones under the influence of 2-propanol in the presence of potassium hydroxide. Bis(1,3-dimethylbenzimidazol-2-ylidene)copper(I) iodide and the polymeric complex of crown-biscarbene with copper(I) iodide show the highest catalytic efficiency.

Keywords

heterocyclic carbene complexes of copper(I) nickel and palladium catalysis reduction of ketones 

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Copyright information

© Springer Science+Business Media, Inc. 2012

Authors and Affiliations

  • N. I. Korotkikh
    • 1
    Email author
  • V. Sh. Saberov
    • 1
  • A. V. Kiselev
    • 1
  • N. V. Glinyanaya
    • 1
  • K. A. Marichev
    • 1
  • T. M. Pekhtereva
    • 1
  • G. V. Dudarenko
    • 2
  • N. A. Bumagin
    • 3
  • O. P. Shvaika
    • 1
  1. 1.L. M. Litvinenko Institute of Physical Organic and Coal ChemistryThe National Academy of Sciences of UkraineDonetskUkraine
  2. 2.Institute of Macromolecular ChemistryThe National Academy of Sciences of UkraineKyivUkraine
  3. 3.M. V. Lomonosov Moscow State UniversityMoscowRussia

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