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Synthesis and crystal structure of a solvate of arsenic 4,6-dimethyl-8-quinolinethiolate

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Chemistry of Heterocyclic Compounds Aims and scope

A crystallosolvate of arsenic 4,6-dimethyl-8-quinolinethiolate, As[4,6-Me2C9H4NS]3⋅CHCl3 has been synthesized. The molecular and crystalline structures of the compound have been determined by X-ray structural analysis. The influence of the composition and structure of the ligand on the geometry of the coordination environment of the central arsenic atom in the investigated crystal structures of intracomplex compounds of 8-quinolinethiols is discussed.

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  1. E. Ya. Silina, S. V. Belyakov, J. V. Ashaks, L. J. Pech, and D. E. Zaruma, Zh. Neorg. Khim., in press.

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The authors are grateful to the Latvian Council of Science for financial support of the investigation.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Riga Technical University, 34 Miera St., Salaspils, LV-2169, Latvia

    E. Silina, J. Ashaks, L. Pech & D. Zaruma

  2. Latvian Institute of Organic Synthesis, 21 Aizkraukles St., Riga, LV-1006, Latvia

    S. Belyakov

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  1. E. Silina
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  2. S. Belyakov
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  3. J. Ashaks
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  4. L. Pech
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  5. D. Zaruma
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Correspondence to E. Silina.

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Dedicated to the memory of Academician E. Lukevics.

J. Ashaks (Deceased).

L. Pech (Deceased).

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1847-1853, December, 2011.

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Silina, E., Belyakov, S., Ashaks, J. et al. Synthesis and crystal structure of a solvate of arsenic 4,6-dimethyl-8-quinolinethiolate. Chem Heterocycl Comp 47, 1544–1550 (2012). https://doi.org/10.1007/s10593-012-0946-x

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  • DOI: https://doi.org/10.1007/s10593-012-0946-x

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