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Chemistry of Heterocyclic Compounds

, Volume 47, Issue 12, pp 1527–1532 | Cite as

Vinylation of pyridylcarboxamides with vinyltrimethoxysilane

  • P. ArsenyanEmail author
  • A. Petrenko
  • S. Belyakov
Article

A convenient method has been developed for the direct N-vinylation of pyridylcarboxamides with vinyltrimethoxysilane in the presence of copper(II) acetate and tetrabutylammonium fluoride. The yield of N-vinylamides depends on the nature of the starting amide and the solvent. The molecular structure of the products was confirmed by X-ray structural analysis.

Keywords

amide copper(II) acetate vinyl amide vinyltrimethoxysilane silane catalysis X-ray structural analysis 

Notes

The work was carried out with the assistance of the European Social Fund (ESF No. 2009/0197/1DP/1.1.1.2.0/09/APIA/VIAA/014), and also a grant from the Latvian Council of Science (No. 09.1588).

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Copyright information

© Springer Science+Business Media, Inc. 2012

Authors and Affiliations

  1. 1.Latvian Institute of Organic SynthesisRigaLatvia

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