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Chemistry of Heterocyclic Compounds

, Volume 47, Issue 11, pp 1345–1352 | Cite as

Novel route to the synthesis of chalcogenolanes, chalcogenanes, and 1,2-dichalcogenaepanes*

  • E. P. LevanovaEmail author
  • V. A. Grabel’nykh
  • A. V. Elaev
  • N. V. Russavskaya
  • L. V. Klyba
  • A. I. Albanov
  • N. A. Korchevin
Article

The saturated heterocyclic compounds C4H8Y, C5H10Y, and C5H10Y2 (Y = Se or Te) have been prepared by the reaction of 1,4-dibromobutane or 1,5-dibromopentane with potassium chalcogenides. The novelty of the route consists of the use of the hydrazine hydrate–KOH system for the reductive generation of potassium selenide, telluride, diselenide or ditelluride from elemental chalcogens.

Keywords

1,2-dichalcogenaepanes chalcogenanes chalcogenonium salts chalcogenolanes hydrazine hydrate–alkali systems 

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Copyright information

© Springer Science+Business Media, Inc. 2012

Authors and Affiliations

  • E. P. Levanova
    • 1
    Email author
  • V. A. Grabel’nykh
    • 1
  • A. V. Elaev
    • 1
  • N. V. Russavskaya
    • 1
  • L. V. Klyba
    • 1
  • A. I. Albanov
    • 1
  • N. A. Korchevin
    • 1
  1. 1.A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of SciencesIrkutskRussia

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