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Chemistry of Heterocyclic Compounds

, Volume 47, Issue 11, pp 1330–1338 | Cite as

Basicity of silatranes (Review)

  • M. G. VoronkovEmail author
  • V. V. Belyaeva
  • K. A. Abzaeva
Article

The silatranes basicity study results are summarized. A large amount of experimental data obtained 25-40 years ago is critically reviewed. It is shown that the reactivity and physicochemical properties of silatranes are determined by their basicity, which depends on the stereoelectronic structure.

Keywords

silatranes complexation center coordination bond electronegativity nucleophilicity proton acceptor silatrane basicity 

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Copyright information

© Springer Science+Business Media, Inc. 2012

Authors and Affiliations

  • M. G. Voronkov
    • 1
    Email author
  • V. V. Belyaeva
    • 1
  • K. A. Abzaeva
    • 1
  1. 1.A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of SciencesIrkutskRussia

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