A general method has been developed for the synthesis of 1H-imidazoles containing a phosphoryl group in positions 2 or 4(5) based on lithium intermediates. The possibility of further functionalization of the ring using electrophiles has also been demonstrated.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 52–62, January 2011.
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Pavlenko, N.V., Oos, T.I., Yagupolskii, Y.L. et al. Novel structural analogs of glyphosate based on azoles. 1. Synthesis of 1H-imidazoles containing carboxyl and phosphoryl groups in the ring. Chem Heterocycl Comp 47, 36–44 (2011). https://doi.org/10.1007/s10593-011-0717-0
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DOI: https://doi.org/10.1007/s10593-011-0717-0