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Synthesis of photochromic bisfulgimides by the condensation of (3Z)-3-[1-(2,5-dimethyl-3-thienyl)-ethylidene]-4-isopropylidene-2,5-furandione with aromatic diamines

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Chemistry of Heterocyclic Compounds Aims and scope

The first representatives of thiophene derivatives with two fulgimide fragments in one molecule have been obtained by the condensation of (3Z)-3-[1-(2,5-dimethyl-3-thienyl)ethylidene]-4-isopropylidene-2,5-furandione with aromatic diamines. The photochromic properties of the obtained compounds have been investigated and the effect of a spacer, linking the two fulgimide fragments, on the reaction rates of photocoloration and photodecoloration of these compounds has been studied.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    S. I. Luyksaar & M. M. Krayushkin

  2. Photochemistry Center, Russian Academy of Sciences, Moscow, 119421, Russia

    Yu. A. Pyankov & V. A. Barachevsky

Authors
  1. S. I. Luyksaar
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  2. M. M. Krayushkin
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  3. Yu. A. Pyankov
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  4. V. A. Barachevsky
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Correspondence to S. I. Luyksaar.

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 1019-1026, July, 2010.

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Luyksaar, S.I., Krayushkin, M.M., Pyankov, Y.A. et al. Synthesis of photochromic bisfulgimides by the condensation of (3Z)-3-[1-(2,5-dimethyl-3-thienyl)-ethylidene]-4-isopropylidene-2,5-furandione with aromatic diamines. Chem Heterocycl Comp 46, 822–828 (2010). https://doi.org/10.1007/s10593-010-0589-8

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  • DOI: https://doi.org/10.1007/s10593-010-0589-8

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