Chemistry of Heterocyclic Compounds

, Volume 45, Issue 10, pp 1190–1196 | Cite as

Synthesis and some chemical conversions of acetylenic derivatives of 1,4-dioxane


The possibility has been shown of synthesizing acetylenic derivatives of 1,4-dioxane in high yield by the interaction of glycidyl ethers of acetylenic alcohols with ethylene bromohydrin in the presence of boron trifluoride etherate. Dehydrobromination of the corresponding bromohydrin was then carried out in the presence of metallic sodium in absolute diethyl ether. Acetylenic derivatives of 1,4-dioxane enter into hydrosilylation, aminomethylation, and diene condensation reactions with the formation of new derivatives of 1,4-dioxane.


acetylenic alcohols diacetylenic derivatives 1,4-dioxanes ethylene bromohydrin aminomethylation diene condensation hydrosilylation 


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Copyright information

© Springer Science+Business Media, Inc. 2009

Authors and Affiliations

  • M. G. Veliev
    • 1
  • M. I. Shatirova
    • 1
  • O. V. Askerov
    • 1
  1. 1.Institute of Polymeric MaterialsNational Academy of Sciences of AzerbaijanSumgaitAzerbaijan

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