The effect of the catalytic characteristics of compounds of niobium(II) and (V) on the duration and the composition of the products during the oxidation of furfural by aqueous hydrogen peroxide was studied. It was established that the process is intermediate in its main characteristics between reactions of the compounds taking place under the conditions of autocatalysis by the acids that are formed and in the presence of the vanadium compounds. The main product of the reaction is 2(5H)-furanone. A method is proposed for its production with yields of up to 60%.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
V. V. Poskonin, Khim. Geterotsikl. Soedin., 386 (2008). [Chem. Heterocycl. Comp., 44, 295 (2008)].
V. V. Poskonin, Dis. Doctor Chem. Sci. [in Russian], Krasnodar (2001).
V. V. Poskonin and L. A. Badovskaya, Khim. Geterotsikl. Soedin., 1462 (1991). [Chem. Heterocycl. Comp., 27, 1171 (1991)].
V. G. Kul'nevich and L. A. Badovskaya, Uspekhi Khimii, 44, 1256 (1975).
L. A. Badovskaya, Dis. Doctor Chem. Sci. [in Russian], Krasnodar (1982).
V. V. Poskonin and L. A. Badovskaya, RF Pat. 1715806; Byul. Izobr., No. 4, 36 (1992).
E. P. Grunskaya, L. A. Badovskaya, and V. V. Poskonin, Khim. Geterotsikl. Soedin., 898 (1998). [Chem. Heterocycl. Comp., 34, 775 (1998)].
V. V. Poskonin, А. В. A. V. Sarkisyan, E. P. Grunskaya, and L. A. Badovskaya, in: Chemistry and Chemical Technology of Furan Compounds [in Russian], Mezhvuz. Sb. Nauch. Tr. Kubanskogo Gos. Tekhnol. Un-ta, Krasnodar (1996), p. 61.
S. P. Gavrilova, Dis. Cand. Chem. Sci. [in Russian], Krasnodar (1980).
S. P. Gavrilova, L. A. Badovskaya, and V. G. Kul'nevich, Kinetika i Kataliz, 20, 1338 (1979).
Ya. A. Ugai, General and Inorganic Chemistry [in Russian], Vysshaya Shkola, Moscow (1997).
G. A. Tolstikov, Hydroperoxide Oxidation Reactions [in Russian], Nauka, Moscow (1976).
G. A. Tolstikov, Uspekhi Khimii, 44, 1208 (1975).
I. I. Vol'nov, Peroxo Complexes of Vanadium, Niobium, and Tantalum [in Russian], Nauka, Moscow (1987).
Yu. Yu. Lur'e, Handbook of Analytical Chemistry [in Russian], Khimiya, Moscow (1979).
Ya. I. Tur'yan, Oxidation–Reduction Reactions and Potentials in Analytical Chemistry [in Russian], Khimiya, Moscow (1989).
Ya. A. Dorfman, G. S. Polimbetova, and D. M. Doroshkevich, Zh. Neorgan. Khim., 41, 658 (1996).
Y. S. Rao, Chem. Rev., 76, 625 (1976).
L. A. Badovskaya, V. M. Latashko, V. V. Poskonin, E. P. Grunskaya, Z. I. Tyukhteneva, S. G. Rudakova, S. A. Pestunova, and A. V. Sarkisyan, Khim. Geterotsikl. Soedin., 1194 (2002). [Chem. Heterocycl. Comp., 38, 1040 (2002)].
L. A. Badovskaya, G. F. Muzychenko, S. V. Abramyants, V. G. Kul'nevich, and V. M. Latashko, USSR Inventor's Certificate No. 470516; Byul. Izobr., No. 18, 34 (1975).
O. R. Mun and C. R. Kim, Hwahakgwa Hwahakgonhak (Chem. and Chem. Eng.), 5, 35 (1992).
Author information
Authors and Affiliations
Corresponding author
Additional information
For Communication 8, see [1].
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1470-1477, October, 2009.
Rights and permissions
About this article
Cite this article
Poskonin, V.V. Catalytic oxidation reactions of furan and hydrofuran compounds 9.* characteristics and synthetic possibilities of the reaction of furan with aqueous hydrogen peroxide in the presence of compounds of niobium (ii) and (v). Chem Heterocycl Comp 45, 1177–1183 (2009). https://doi.org/10.1007/s10593-010-0404-6
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10593-010-0404-6