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Reactions of 1,3,5-triazinylnitro-formaldoximes. 2*. The reaction of 1,3,5-triazinylnitroformaldoximes with monosubstituted acetylenes

  • V. V. BakharevEmail author
  • A. A. Gidaspov
  • E. V. Peresedova
  • D. B. Krivolapov
  • E. V. Mironova
  • I. A. Litvinov
Article

1,3,5-Triazinylnitrile oxides were prepared in situ from 2-R-4-R′-1,3,5-triazin-6-ylnitroformaldoximes and were treated with substituted acetylenes to give 3,5-disubstituted isoxazoles. The X-ray data obtained for 5-hydroxymethyl-3-(4′-dimethylamino-2′-methoxy-1,3,5-triazin-6′-yl)isoxazole is discussed.

Keywords

3,5-disubstituted isoxazoles acetylene derivatives 1,3,5-triazinylnitrile oxides 1,3,5-tri-azinylnitroformaldoximes 

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Copyright information

© Springer Science+Business Media, Inc. 2009

Authors and Affiliations

  • V. V. Bakharev
    • 1
    Email author
  • A. A. Gidaspov
    • 1
  • E. V. Peresedova
    • 1
  • D. B. Krivolapov
    • 2
  • E. V. Mironova
    • 2
  • I. A. Litvinov
    • 2
  1. 1.Samara State Technical UniversitySamaraRussia
  2. 2.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan Science Center of the Russian Academy of SciencesTatarstan RepublicRussia

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