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Structural investigation of 1-(N,N-dimethylaminomethyl)-spirobi(3-oxo-2,5-dioxa-1-silacyclo-pentan)ates

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Chemistry of Heterocyclic Compounds Aims and scope

An Erratum to this article was published on 01 January 2009

1-[(N,N-Dimethyl)aminomethyl]spirobi(3-oxo-2,5-dioxa-1-silacyclopentan)ate and 1-(N,N-dimethyl)-aminomethyl]spirobi(4,4-dimethyl-3-oxo-2,5-dioxa-1-silacyclopentan)ate are representatives of amino-methylspirobi(3-oxo-2,5-dioxa-1-silacyclopentan)ates, which are electrostatically stabilized silanates (ES silanates). X-ray diffraction structural analysis and quantum-chemical calculations were used in a structural study of these compounds. The factors affecting the geometry of these molecules are discussed.

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Authors and Affiliations

  1. Latvian Institute of Organic Chemistry, LV-1006, Riga, Latvia

    S. Belyakov, S. Zheimote, M. Fleisher & E. Lukevics

  2. A. S. Pushkin Brest State University, 224665, Brest, Belarus

    N. Erchak

  3. University of Podlasie, 08-110, Siedlce, Poland

    N. Erchak

Authors
  1. S. Belyakov
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  2. N. Erchak
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  3. S. Zheimote
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  4. M. Fleisher
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  5. E. Lukevics
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Correspondence to S. Belyakov.

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Dedicated to Academician Janis Stradins on the Occasion of His 75th jubilee.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1873–1881, December, 2008.

An erratum to this article can be found at http://dx.doi.org/10.1007/s10593-009-0241-7

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Belyakov, S., Erchak, N., Zheimote, S. et al. Structural investigation of 1-(N,N-dimethylaminomethyl)-spirobi(3-oxo-2,5-dioxa-1-silacyclo-pentan)ates. Chem Heterocycl Comp 44, 1520–1526 (2008). https://doi.org/10.1007/s10593-009-0218-6

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  • DOI: https://doi.org/10.1007/s10593-009-0218-6

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