Chemistry of Heterocyclic Compounds

, Volume 44, Issue 11, pp 1355–1358 | Cite as

Synthesis and halocyclization of 2-alkenylthioquinolines

  • D. G. Kim

Bromination of 2-vinylthioquinoline and cis-2-styrylthioquinoline with molecular bromine leads to the formation of 2-bromo(3-phenyl)-2,3-dihydrothiazolo[3,2-a]quinolinium bromides, and of 2-allyl-thioquinoline to a mixture of 2-and 3-bromomethyl-2,3-dihydrothiazolo[3,2-a]quinolinium bromides. Iodine reacts with allylthioquinoline with the formation of 3-iodomethyl-2,3-dihydrothiazolo-[3,2-a]quinolinium triiodide.


2-alkenylthioquinolines thiazolo[3,2-a]quinolinium halides halocyclization 


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  1. 1.
    D. G. Kim, A. V. Sashin, V. A. Kozlovskaya, and I. N. Andreeva, Khim. Geterotsikl. Soedin., 1252 (1996). [Chem. Heterocycl. Comp., 32, 1075 (1996)].Google Scholar
  2. 2.
    D. Kim, G. G. Skvortsova, and L. M. Pachkova, Abstracts, IV All-Union Conference on the Chemistry of Acetylene and Its Derivatives, Baku (1979), Part. 1, p. 134.Google Scholar
  3. 3.
    G. G. Skvortsova, D. G. Kim, and L. V. Andriyankova, Khim. Geterotsikl. Soedin., 364 (1978). [Chem. Heterocycl. Comp., 14, 297 (1978)].Google Scholar
  4. 4.
    W. E. Truce and J. A. Simms, J. Am. Chem. Soc., 78, 2756 (1956).CrossRefGoogle Scholar
  5. 5.
    B. A. Trofimov, Usp. Khim., 50, 248 (1981).Google Scholar
  6. 6.
    B. A. Trofimov and S. V. Amosova, Divinyl Sulfide and Its Derivatives [in Russian], Nauka, Novosibirsk (1983), p. 42.Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2008

Authors and Affiliations

  1. 1.South Ural State UniversityChelyabinskRussia

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