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Chemistry of Heterocyclic Compounds

, Volume 44, Issue 11, pp 1379–1383 | Cite as

Synthesis of 1,3-diazapyrenes and 1,3,7-triazapyrenes by the reaction of 1,8-naphthalenediamine with triazine in the presence of carbonyl compounds or benzonitrile in polyphosphoric acid

  • A. V. Aksenov
  • I. V. Aksenova
  • A. S. Lyakhovnenko
  • N. A. Aksenov
Article

A novel three-component synthesis has been developed for 1,3-diazapyrenes based on the reaction of 1,8-naphthalenediamine with triazine and carbonyl compounds in polyphosphoric acid (PPA). The use of benzonitrile in place of the carbonyl compounds in this reaction gives 6-phenyl-1,3,7-triazapyrenes.

Keywords

1,3-diazapyrenes 1,8-naphthalenediamine perimidines PPA 1,3,7-triazapyrenes 1,3,5-triazine annelation 

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Copyright information

© Springer Science+Business Media, Inc. 2008

Authors and Affiliations

  • A. V. Aksenov
    • 1
  • I. V. Aksenova
    • 1
  • A. S. Lyakhovnenko
    • 1
  • N. A. Aksenov
    • 1
  1. 1.Stavropol State UniversityStavropolRussia

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