The action of 2-, 3-, and 4-pyridinecarboxaldehydes on 1,8-bis(dimethylamino)-2-lithium-and 1,8-bis(dimethylamino)-2,7-dilithiumnaphthalenes gave secondary mono-and dicarbinols containing pyridylcarbinol groups at C-2 and C-7 of the proton sponge. Spectral and X-ray diffraction structural data were used to study the molecular structure of these products.
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Dedicated to Academician B. A. Trofimov, an outstanding organic chemist, who has made a major contribution to the chemistry of acetylenes and nitrogen heterocycles on the occasion of his seventieth jubilee.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1409–1417, September, 2008.
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Degtyarev, A.V., Pozharskii, A.F. Proton sponges-based (2-naphthyl)pyridylmethanol. Chem Heterocycl Comp 44, 1138–1145 (2008). https://doi.org/10.1007/s10593-008-0164-8
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DOI: https://doi.org/10.1007/s10593-008-0164-8