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Synthesis and crystal structure of 1-(4-fluorophenyl)-and 1-(4-dimethylamino)phenylgermatranes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The X-ray crystal structure of 1-(4-fluorophenyl)-and 1-(4-dimethylaminophenyl)germatranes reveals that the germanium atom is pentacoordinated and adopts a trigonal bipyramidal geometry. The fluorophenyl and dimethylaminophenyl groups and the nitrogen atom each occupy an apical position with the transannular N→Ge bond of 2.192(3) and 2.249(3) Å; the deviation of the Ge atom from the O(2)-O(8)-O(9) plane is 0.2306(4) and 0.2693(3) Å, correspondingly.

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Authors and Affiliations

  1. Latvian Institute of Organic Synthesis, Riga, LV-1006, Latvia

    E. Lukevics, L. Ignatovich, T. Shul’ga & S. Belyakov

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  1. E. Lukevics
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  2. L. Ignatovich
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  3. T. Shul’ga
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  4. S. Belyakov
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Correspondence to L. Ignatovich.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 776–781, May, 2008.

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Lukevics, E., Ignatovich, L., Shul’ga, T. et al. Synthesis and crystal structure of 1-(4-fluorophenyl)-and 1-(4-dimethylamino)phenylgermatranes. Chem Heterocycl Comp 44, 615–620 (2008). https://doi.org/10.1007/s10593-008-0082-9

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  • DOI: https://doi.org/10.1007/s10593-008-0082-9

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