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New functionalized dithia-12(13)-crown-4 ethers: Synthesis, complex formation, and extraction capacity

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

1,4-Dioxa-7,10-dithiacyclododecane-8-carbonitrile, 1,4-dioxa-7,11-dithiacyclotridecan-9-one, its 2,4-dinitrophenylhydrazone, and unsubstituted 7,10-dithia-12-crown-4 were synthesized. The complexing ability of the four synthesized dioxadithiacrown compounds toward Ag(I), Pb(II), Hg(II), and Cd(II) ions was assessed by 1H NMR. The extracting ability of the three dioxadithiacrown compounds with respect to the Sn(II) ion from aqueous solutions was studied. The thermal stability of 1,4-dioxa-7,10-dithia-cyclododecane and the corresponding 8-carbonitrile was investigated.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, Moscow, 119992, Russia

    A. A. Zenina, E. V. Rakhmanov, A. A. Bobyleva, E. V. Lukovskaya, A. A. Abramov & A. V. Anisimov

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 117071

    L. G. Kuzmina

Authors
  1. A. A. Zenina
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  2. E. V. Rakhmanov
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  3. A. A. Bobyleva
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  4. E. V. Lukovskaya
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  5. L. G. Kuzmina
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  6. A. A. Abramov
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  7. A. V. Anisimov
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 992–1000, July, 2007.

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Zenina, A.A., Rakhmanov, E.V., Bobyleva, A.A. et al. New functionalized dithia-12(13)-crown-4 ethers: Synthesis, complex formation, and extraction capacity. Chem Heterocycl Compd 43, 835–843 (2007). https://doi.org/10.1007/s10593-007-0133-7

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  • DOI: https://doi.org/10.1007/s10593-007-0133-7

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