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Chemistry of Heterocyclic Compounds

, Volume 43, Issue 7, pp 835–843 | Cite as

New functionalized dithia-12(13)-crown-4 ethers: Synthesis, complex formation, and extraction capacity

  • A. A. Zenina
  • E. V. Rakhmanov
  • A. A. Bobyleva
  • E. V. Lukovskaya
  • L. G. Kuzmina
  • A. A. Abramov
  • A. V. Anisimov
Article

Abstract

1,4-Dioxa-7,10-dithiacyclododecane-8-carbonitrile, 1,4-dioxa-7,11-dithiacyclotridecan-9-one, its 2,4-dinitrophenylhydrazone, and unsubstituted 7,10-dithia-12-crown-4 were synthesized. The complexing ability of the four synthesized dioxadithiacrown compounds toward Ag(I), Pb(II), Hg(II), and Cd(II) ions was assessed by 1H NMR. The extracting ability of the three dioxadithiacrown compounds with respect to the Sn(II) ion from aqueous solutions was studied. The thermal stability of 1,4-dioxa-7,10-dithia-cyclododecane and the corresponding 8-carbonitrile was investigated.

Keywords

dithia-12(13)-crown-4 ethers Ag(I), Pb(II), Hg(II), Sn(II) ions complexing synthesis thermal stability extraction 1H NMR spectroscopy X-ray crystallographic analysis 

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Copyright information

© Springer Science+Business Media, Inc. 2007

Authors and Affiliations

  • A. A. Zenina
    • 1
  • E. V. Rakhmanov
    • 1
  • A. A. Bobyleva
    • 1
  • E. V. Lukovskaya
    • 1
  • L. G. Kuzmina
    • 2
  • A. A. Abramov
    • 1
  • A. V. Anisimov
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityMoscowRussia
  2. 2.N. S. Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscow

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