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Synthesis and structure of tris(5-phenyltetrazol-1-yl)methane

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The interaction of 5-phenyltetrazolate anion with chloroform in strongly alkaline medium leads to the formation of tris(5-phenyltetrazol-1-yl)methane and 2-dichloromethyl-5-phenyltetrazole. The structures of tris(5-phenyltetrazol-1-yl)-methane and of its isomer tris(5-phenyltetrazol-2-yl)methane have been investigated by X-ray structural analysis and theoretical calculations carried out on the B3LYP/6-31G** basis.

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Authors and Affiliations

  1. Saint Petersburg State Technological Institute (Technical University), Saint Petersburg, 190013, Russia

    R. E. Trifonov & V. A. Ostrovskii

  2. V. A. Engelgardt Institute of Molecular Biology, Russian Academy of Sciences, Moscow, 119991

    G. V. Gurskaya

  3. Department of Theoretical Chemistry, Chemical Center, Lund University, Lund, S-221 00, Sweden

    A. V. Gaenko

  4. L. Ya. Karpov Research Institute for Physical Chemistry, Moscow, 105064, Russia

    V. E. Zavodnik

Authors
  1. R. E. Trifonov
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  2. G. V. Gurskaya
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  3. A. V. Gaenko
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  4. V. E. Zavodnik
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  5. V. A. Ostrovskii
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 398–404, March, 2007.

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Trifonov, R.E., Gurskaya, G.V., Gaenko, A.V. et al. Synthesis and structure of tris(5-phenyltetrazol-1-yl)methane. Chem Heterocycl Compd 43, 320–325 (2007). https://doi.org/10.1007/s10593-007-0048-3

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  • DOI: https://doi.org/10.1007/s10593-007-0048-3

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